Rhodium-catalyzed intermolecular chelation controlled alkene and alkyne hydroacylation: synthetic scope of beta-S-substituted aldehyde substrates.
The use of beta-S-substituted aldehydes in rhodium-catalyzed intermolecular hydroacylation reactions is reported. Aldehydes substituted with either sulfide or thioacetal groups undergo efficient hydroacylation with a variety of electron-poor alkenes, such as enoates, in Stetter-like processes and wi...
Автори: | Willis, M, Randell-Sly, H, Woodward, R, McNally, S, Currie, G |
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Формат: | Journal article |
Мова: | English |
Опубліковано: |
2006
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