Topochemical reactions of layered transition-metal oxides

Low-temperature topochemical reactions performed on complex transition metal oxides allow the synthesis of novel, metastable phases often with unusual transition metal oxidation states and/or coordination geometries. Layered materials offer many opportunities to control the structural and chemical s...

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Bibliografske podrobnosti
Glavni avtor: Hayward, M
Format: Journal article
Jezik:English
Izdano: Institute of Physics Publishing 2014
Opis
Izvleček:Low-temperature topochemical reactions performed on complex transition metal oxides allow the synthesis of novel, metastable phases often with unusual transition metal oxidation states and/or coordination geometries. Layered materials offer many opportunities to control the structural and chemical selectivity of these types of reactions to allow the preparation of desired phases in a rational manner. Using complex oxides adopting Ruddlesden-Popper type structures as examples, recent progress in the low-temperature topochemical reduction by anion de-intercalation, and oxidation by anion insertion, is reviewed. © 2014 IOP Publishing Ltd.