Topochemical reactions of layered transition-metal oxides
Low-temperature topochemical reactions performed on complex transition metal oxides allow the synthesis of novel, metastable phases often with unusual transition metal oxidation states and/or coordination geometries. Layered materials offer many opportunities to control the structural and chemical s...
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| Format: | Journal article |
| Language: | English |
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Institute of Physics Publishing
2014
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| _version_ | 1797104560751247360 |
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| author | Hayward, M |
| author_facet | Hayward, M |
| author_sort | Hayward, M |
| collection | OXFORD |
| description | Low-temperature topochemical reactions performed on complex transition metal oxides allow the synthesis of novel, metastable phases often with unusual transition metal oxidation states and/or coordination geometries. Layered materials offer many opportunities to control the structural and chemical selectivity of these types of reactions to allow the preparation of desired phases in a rational manner. Using complex oxides adopting Ruddlesden-Popper type structures as examples, recent progress in the low-temperature topochemical reduction by anion de-intercalation, and oxidation by anion insertion, is reviewed. © 2014 IOP Publishing Ltd. |
| first_indexed | 2024-03-07T06:35:28Z |
| format | Journal article |
| id | oxford-uuid:f77920af-7c78-4c96-a2fc-04569f2512f8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:35:28Z |
| publishDate | 2014 |
| publisher | Institute of Physics Publishing |
| record_format | dspace |
| spelling | oxford-uuid:f77920af-7c78-4c96-a2fc-04569f2512f82022-03-27T12:42:55ZTopochemical reactions of layered transition-metal oxidesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f77920af-7c78-4c96-a2fc-04569f2512f8EnglishSymplectic Elements at OxfordInstitute of Physics Publishing2014Hayward, MLow-temperature topochemical reactions performed on complex transition metal oxides allow the synthesis of novel, metastable phases often with unusual transition metal oxidation states and/or coordination geometries. Layered materials offer many opportunities to control the structural and chemical selectivity of these types of reactions to allow the preparation of desired phases in a rational manner. Using complex oxides adopting Ruddlesden-Popper type structures as examples, recent progress in the low-temperature topochemical reduction by anion de-intercalation, and oxidation by anion insertion, is reviewed. © 2014 IOP Publishing Ltd. |
| spellingShingle | Hayward, M Topochemical reactions of layered transition-metal oxides |
| title | Topochemical reactions of layered transition-metal oxides |
| title_full | Topochemical reactions of layered transition-metal oxides |
| title_fullStr | Topochemical reactions of layered transition-metal oxides |
| title_full_unstemmed | Topochemical reactions of layered transition-metal oxides |
| title_short | Topochemical reactions of layered transition-metal oxides |
| title_sort | topochemical reactions of layered transition metal oxides |
| work_keys_str_mv | AT haywardm topochemicalreactionsoflayeredtransitionmetaloxides |