Numerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical properties
A general mathematical model for partially blocked electrodes (PBEs) taking into account the finite volume and height of the blocking units has been developed and solved using numerical simulation. The electrochemical behaviour of this model was studied and compared to the common 'flat block�...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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2005
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| _version_ | 1797104610765176832 |
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| author | Chevallier, F Davies, T Klymenko, O Jiang, L Jones, T Compton, R |
| author_facet | Chevallier, F Davies, T Klymenko, O Jiang, L Jones, T Compton, R |
| author_sort | Chevallier, F |
| collection | OXFORD |
| description | A general mathematical model for partially blocked electrodes (PBEs) taking into account the finite volume and height of the blocking units has been developed and solved using numerical simulation. The electrochemical behaviour of this model was studied and compared to the common 'flat block' approach in which the blocks are assumed to have zero height to highlight the main differences and explain their origins. © 2004 Elsevier B.V. All rights reserved. |
| first_indexed | 2024-03-07T06:36:08Z |
| format | Journal article |
| id | oxford-uuid:f7b1aee5-b5ed-4ee7-a3af-eeff5d810dca |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:36:08Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:f7b1aee5-b5ed-4ee7-a3af-eeff5d810dca2022-03-27T12:44:37ZNumerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical propertiesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f7b1aee5-b5ed-4ee7-a3af-eeff5d810dcaEnglishSymplectic Elements at Oxford2005Chevallier, FDavies, TKlymenko, OJiang, LJones, TCompton, RA general mathematical model for partially blocked electrodes (PBEs) taking into account the finite volume and height of the blocking units has been developed and solved using numerical simulation. The electrochemical behaviour of this model was studied and compared to the common 'flat block' approach in which the blocks are assumed to have zero height to highlight the main differences and explain their origins. © 2004 Elsevier B.V. All rights reserved. |
| spellingShingle | Chevallier, F Davies, T Klymenko, O Jiang, L Jones, T Compton, R Numerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical properties |
| title | Numerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical properties |
| title_full | Numerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical properties |
| title_fullStr | Numerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical properties |
| title_full_unstemmed | Numerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical properties |
| title_short | Numerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical properties |
| title_sort | numerical simulation of partially blocked electrodes under cyclic voltammetry conditions influence of the block unit geometry on the global electrochemical properties |
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