Numerical simulation of partially blocked electrodes under cyclic voltammetry conditions: influence of the block unit geometry on the global electrochemical properties
A general mathematical model for partially blocked electrodes (PBEs) taking into account the finite volume and height of the blocking units has been developed and solved using numerical simulation. The electrochemical behaviour of this model was studied and compared to the common 'flat block...
Main Authors: | Chevallier, F, Davies, T, Klymenko, O, Jiang, L, Jones, T, Compton, R |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2005
|
Similar Items
-
Experimental cyclic voltammetry at partially blocked electrodes: Elevated cylindrical blocks - Significantly blocked and non-flat electrodes can appear to show one-dimensional diffusion
by: Chevallier, F, et al.
Published: (2006) -
Influence of the block geometry on the voltammetric response of partially blocked electrodes: Application to interfacial liquid-liquid kinetics of aqueous vitamin B-12S with random arrays of femtolitre microdroplets of dibromocyclohexane
by: Chevallier, F, et al.
Published: (2005) -
Computational and experimental study of the cyclic voltammetry response of partially blocked electrodes. Part 1. Nonoverlapping, uniformly distributed blocking systems
by: Brookes, B, et al.
Published: (2003) -
A computational and experimental study of the cyclic voltammetry response of partially blocked electrodes. Part II: Randomly distributed and overlapping blocking systems
by: Davies, T, et al.
Published: (2003) -
Mathematical modelling and numerical simulation of cyclic voltammetry at an electrode covered with an insulating film containing cylindrical micropores
by: Chevallier, F, et al.
Published: (2006)