Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis.
The coordination chemistry and catalytic applications of organometallic and related lanthanide complexes bearing chiral oxazoline ligands is an area that has been largely underdeveloped, in comparison to complexes based upon lanthanide triflates for use in Lewis acid catalysis. In this article we re...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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Royal Society of Chemistry
2014
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| _version_ | 1797104677019451392 |
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| author | Bennett, S Core, B Blake, M Pope, S Mountford, P Ward, B |
| author_facet | Bennett, S Core, B Blake, M Pope, S Mountford, P Ward, B |
| author_sort | Bennett, S |
| collection | OXFORD |
| description | The coordination chemistry and catalytic applications of organometallic and related lanthanide complexes bearing chiral oxazoline ligands is an area that has been largely underdeveloped, in comparison to complexes based upon lanthanide triflates for use in Lewis acid catalysis. In this article we report on the coordination chemistry of the bis(oxazolinylphenyl)amide (BOPA) ligand with lanthanide alkyl and amide co-ligands (Ln = Y, La, Pr, Nd, Sm). Their structural and spectroscopic characterisation are reported, including an assessment of their photophysical properties using luminescence spectroscopy, and are supported by density functional calculations. The application of these complexes in the hydroamination/cyclisation of aminoalkenes, and in the ring-opening polymerisation of rac-lactide is reported. |
| first_indexed | 2024-03-07T06:36:55Z |
| format | Journal article |
| id | oxford-uuid:f7f955fc-33b4-4d06-a6ad-9e7c225e03b1 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:36:55Z |
| publishDate | 2014 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:f7f955fc-33b4-4d06-a6ad-9e7c225e03b12022-03-27T12:46:46ZChiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f7f955fc-33b4-4d06-a6ad-9e7c225e03b1EnglishSymplectic Elements at OxfordRoyal Society of Chemistry2014Bennett, SCore, BBlake, MPope, SMountford, PWard, BThe coordination chemistry and catalytic applications of organometallic and related lanthanide complexes bearing chiral oxazoline ligands is an area that has been largely underdeveloped, in comparison to complexes based upon lanthanide triflates for use in Lewis acid catalysis. In this article we report on the coordination chemistry of the bis(oxazolinylphenyl)amide (BOPA) ligand with lanthanide alkyl and amide co-ligands (Ln = Y, La, Pr, Nd, Sm). Their structural and spectroscopic characterisation are reported, including an assessment of their photophysical properties using luminescence spectroscopy, and are supported by density functional calculations. The application of these complexes in the hydroamination/cyclisation of aminoalkenes, and in the ring-opening polymerisation of rac-lactide is reported. |
| spellingShingle | Bennett, S Core, B Blake, M Pope, S Mountford, P Ward, B Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis. |
| title | Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis. |
| title_full | Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis. |
| title_fullStr | Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis. |
| title_full_unstemmed | Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis. |
| title_short | Chiral lanthanide complexes: coordination chemistry, spectroscopy, and catalysis. |
| title_sort | chiral lanthanide complexes coordination chemistry spectroscopy and catalysis |
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