Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation

Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation

Axially chiral biaryls, as exemplified by 1,1’-bi-2-naphthol (BINOL), are key components of catalysts, natural products and medicines. These materials are synthesized conventionally in enantioenriched form through metal- mediated cross coupling, de novo construction of an aromatic ring, point-to-axi...

Bibliografske podrobnosti
Main Authors:	Jolliffe, J, Armstrong, R, Smith, M
Format:	Journal article
Izdano:	Nature Publishing Group 2017

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