Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation

Catalytic enantioselective synthesis of atropisomeric biaryls by a cation-directed O-alkylation

Axially chiral biaryls, as exemplified by 1,1’-bi-2-naphthol (BINOL), are key components of catalysts, natural products and medicines. These materials are synthesized conventionally in enantioenriched form through metal- mediated cross coupling, de novo construction of an aromatic ring, point-to-axi...

书目详细资料
Main Authors:	Jolliffe, J, Armstrong, R, Smith, M
格式:	Journal article
出版:	Nature Publishing Group 2017

相似书籍

Deracemization of Atropisomeric Biaryls Enabled by Copper Catalysis
由: Jie Zhang, et al.
出版: (2024-01-01)

Construction of Non-Biaryl Atropisomeric Amide Scaffolds Bearing a C–N Axis via Enantioselective Catalysis
由: Xiao Xiao, et al.
出版: (2022-10-01)

Enantioselective synthesis of non-biaryl atropisomers
由: Fugard, A
出版: (2019)

Frontier molecular orbital effects control the hole-catalyzed racemization of atropisomeric biaryls
由: Tan, J, et al.
出版: (2019)

Enantioselective synthesis of atropisomeric indoles via iron-catalysed oxidative cross-coupling
由: Surgenor, RR, et al.
出版: (2022)

Catalytic enantioselective synthesis of indanes by a cation-directed 5-endo-trig cyclization
由: Johnston, C, et al.
出版: (2015)

Cation-directed enantioselective N-functionalization of pyrroles
由: Armstrong, R, et al.
出版: (2016)

Organocatalyzed diastereo- and enantioselective synthesis of N–N atropisomeric isoindolinones bearing central chirality
由: Xingguang Li, et al.
出版: (2025-02-01)

Cation-directed enantioselective synthesis of quaternary-substituted indolenines
由: Li, M, et al.
出版: (2013)

New cation-mediated enantioselective transformations and catalytic enantioselective photocyclization
由: Jones, BA
出版: (2021)

Asymmetric synthesis of axially chiral biaryls and fluoroallenes through rhodium-catalyzed enantioselective transformations
由: Ng, Jia Sheng
出版: (2020)

Atropisomeric amides as chiral ligands: using (-)-sparteine-directed enantioselective silylation to control the conformation of a stereogenic axis
由: Clayden, J, et al.
出版: (2000)

Catalytic Enantioselective Cyclization/Cross-Coupling with Alkyl Electrophiles
由: Cong, Huan, et al.
出版: (2015)

Enantioselective synthesis of 4- and 6-azaindolines by a cation-directed cyclization
由: Smith, M, et al.
出版: (2016)

Cation-directed atropselective synthesis of BINOL derivatives
由: Jolliffe, JD
出版: (2017)

Enantioselective construction of ortho-sulfur- or nitrogen-substituted axially chiral biaryls and asymmetric synthesis of isoplagiochin D
由: He Yang, et al.
出版: (2022-08-01)

Catalytic Enantioselective Alkylation of Indoles with trans-4-Methylthio-β-Nitrostyrene
由: Isabel Méndez, et al.
出版: (2020-10-01)

Atropisomerism in Styrene: Synthesis, Stability, and Applications
由: Jia Feng, et al.
出版: (2021-01-01)

Catalytic enantioselective synthesis of naturally occurring butenolides via hetero-allylic alkylation and ring closing metathesis.
由: Mao, B, et al.
出版: (2011)

Synthesis of Indenones via Persulfate Promoted Radical Alkylation/Cyclization of Biaryl Ynones with 1,4-Dihydropyridines
由: Wanwan Wang, et al.
出版: (2024-01-01)

Synthesis and applications of atropisomeric quinazolinone phosphine ligands
由: Dai, Xuedong, 1970-
出版: (2009)

Catalytic enantioselective synthesis of heterobiaryl atropisomers
由: Surgenor, R
出版: (2021)

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd- Catalyzed Suzuki-Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations
由: Shen, Xiaoqiang, et al.
出版: (2012)

Catalytic enantioselective total synthesis of hodgkinsine B.
由: Snell, R, et al.
出版: (2011)

Catalytic enantioselective synthesis of P-stereogenic compounds.
由: Harvey, J, et al.
出版: (2010)

Catalytic enantioselective alkylation of sulfenate anions to chiral heterocyclic sulfoxides using halogenated pentanidium salts
由: Zong, Lili, et al.
出版: (2015)

Cobalt-catalyzed enantioselective directed C-H alkylation of indole with styrenes
由: Lee, Pin-Sheng, et al.
出版: (2015)

Atropostatin: Design and Total Synthesis of an Atropisomeric Lactone–Atorvastatin Prodrug
由: Daniel Pecorari, et al.
出版: (2023-04-01)

Alkylation of phenylglycinol-derived bicyclic lactams. Enantioselective synthesis of 3-alkylpiperidines
由: Mercedes Amat, et al.
出版: (2005-03-01)

Catalytic enantioselective electrocyclic cascades
由: Maciver, E, et al.
出版: (2011)

The direct catalytic enantioselective synthesis of protected aryl beta-hydroxy-alpha-amino acids.
由: Willis, M, et al.
出版: (2005)

Catalytic asymmetric 6pi electrocyclization: enantioselective synthesis of functionalized indolines.
由: Maciver, E, et al.
出版: (2009)

Structural studies on biaryl phosphines and palladium complexes composed of biaryl phosphines
由: Barder, Timothy E
出版: (2007)

Catalytic intramolecular ketone hydroacylation: enantioselective synthesis of phthalides.
由: Willis, M
出版: (2010)

Atroposelective hydroarylation of biaryl phosphines directed by phosphorus centres
由: Zexian Li, et al.
出版: (2023-12-01)

Development of bifunctional organic superbases for catalytic enantioselective synthesis
由: Rozsar, D
出版: (2024)

One-pot catalytic enantioselective synthesis of 2-pyrazolines
由: Thomson, C, et al.
出版: (2019)

Cation-controlled diastereo- and enantioselective synthesis of indolines: an autocatalytic process
由: Sharma, K
出版: (2014)

Asymmetric synthesis of enantiomerically enriched atropisomeric amides by desymmetrisation of N,N-dialkylmesitamides
由: Clayden, J, et al.
出版: (2001)

Direct catalytic enantioselective Mannich reactions: synthesis of protected anti-alpha,beta-diamino acids.
由: Cutting, G, et al.
出版: (2007)