Structural effects of hydrostatic pressure in orthorhombic La2-xSrxCuO4.
We have investigated the effect of hydrostatic pressure on the structure of orthorhombic La2-xSrxCuO4 between 1 atm and 0.6 GPa, using neutron powder diffraction. Increasing pressure causes the tilt angle of CuO6 octahedra to decrease, leading to a transition to tetragonal symmetry. There is a stron...
Main Authors: | , , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
1994
|
_version_ | 1797104963849027584 |
---|---|
author | Takahashi, H Shaked, H Hunter, B Radaelli, P Hitterman, R Hinks, D Jorgensen, J |
author_facet | Takahashi, H Shaked, H Hunter, B Radaelli, P Hitterman, R Hinks, D Jorgensen, J |
author_sort | Takahashi, H |
collection | OXFORD |
description | We have investigated the effect of hydrostatic pressure on the structure of orthorhombic La2-xSrxCuO4 between 1 atm and 0.6 GPa, using neutron powder diffraction. Increasing pressure causes the tilt angle of CuO6 octahedra to decrease, leading to a transition to tetragonal symmetry. There is a strong compressibility anisotropy for the orthorhombic structure. Order parameters for the transition versus pressure are consistent with Landau theory for a second-order transition. It is shown that this transition can be universally scaled over (x,T,P) space in the context of Landau theory. We conclude that Tc varies inversely with the tilt angle and is maximum for the tetragonal structure, i.e., for flat and square CuO2 planes, for this compound. © 1994 The American Physical Society. |
first_indexed | 2024-03-07T06:40:50Z |
format | Journal article |
id | oxford-uuid:f93653c8-4ee0-476b-bf73-4c94b2c55007 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T06:40:50Z |
publishDate | 1994 |
record_format | dspace |
spelling | oxford-uuid:f93653c8-4ee0-476b-bf73-4c94b2c550072022-03-27T12:56:19ZStructural effects of hydrostatic pressure in orthorhombic La2-xSrxCuO4.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f93653c8-4ee0-476b-bf73-4c94b2c55007EnglishSymplectic Elements at Oxford1994Takahashi, HShaked, HHunter, BRadaelli, PHitterman, RHinks, DJorgensen, JWe have investigated the effect of hydrostatic pressure on the structure of orthorhombic La2-xSrxCuO4 between 1 atm and 0.6 GPa, using neutron powder diffraction. Increasing pressure causes the tilt angle of CuO6 octahedra to decrease, leading to a transition to tetragonal symmetry. There is a strong compressibility anisotropy for the orthorhombic structure. Order parameters for the transition versus pressure are consistent with Landau theory for a second-order transition. It is shown that this transition can be universally scaled over (x,T,P) space in the context of Landau theory. We conclude that Tc varies inversely with the tilt angle and is maximum for the tetragonal structure, i.e., for flat and square CuO2 planes, for this compound. © 1994 The American Physical Society. |
spellingShingle | Takahashi, H Shaked, H Hunter, B Radaelli, P Hitterman, R Hinks, D Jorgensen, J Structural effects of hydrostatic pressure in orthorhombic La2-xSrxCuO4. |
title | Structural effects of hydrostatic pressure in orthorhombic La2-xSrxCuO4. |
title_full | Structural effects of hydrostatic pressure in orthorhombic La2-xSrxCuO4. |
title_fullStr | Structural effects of hydrostatic pressure in orthorhombic La2-xSrxCuO4. |
title_full_unstemmed | Structural effects of hydrostatic pressure in orthorhombic La2-xSrxCuO4. |
title_short | Structural effects of hydrostatic pressure in orthorhombic La2-xSrxCuO4. |
title_sort | structural effects of hydrostatic pressure in orthorhombic la2 xsrxcuo4 |
work_keys_str_mv | AT takahashih structuraleffectsofhydrostaticpressureinorthorhombicla2xsrxcuo4 AT shakedh structuraleffectsofhydrostaticpressureinorthorhombicla2xsrxcuo4 AT hunterb structuraleffectsofhydrostaticpressureinorthorhombicla2xsrxcuo4 AT radaellip structuraleffectsofhydrostaticpressureinorthorhombicla2xsrxcuo4 AT hittermanr structuraleffectsofhydrostaticpressureinorthorhombicla2xsrxcuo4 AT hinksd structuraleffectsofhydrostaticpressureinorthorhombicla2xsrxcuo4 AT jorgensenj structuraleffectsofhydrostaticpressureinorthorhombicla2xsrxcuo4 |