Unexpected features of stretched Si-H...Mo beta-agostic interactions.
Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2004
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