Conformational control in the SuperQuat chiral auxiliary 5,5-dimethyl-4-iso-propyloxazolidin-2-one induces the iso-propyl group to mimic a tert-butyl group
1H NMR nOe spectroscopic studies reveal that conformational control in the enolates of N-acyl-5,5-dimethyl-4-iso-propyloxazolidin-2-ones ensures that the stereodirecting effect of its 4-iso-propyl-5,5-dimethyl functional group affords superior levels of facial selectivity normally associated with en...
| Principais autores: | , , , , |
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| Formato: | Journal article |
| Idioma: | English |
| Publicado em: |
2000
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| _version_ | 1826306040114708480 |
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| author | Bull, S Davies, S Key, MS Nicholson, R Savory, E |
| author_facet | Bull, S Davies, S Key, MS Nicholson, R Savory, E |
| author_sort | Bull, S |
| collection | OXFORD |
| description | 1H NMR nOe spectroscopic studies reveal that conformational control in the enolates of N-acyl-5,5-dimethyl-4-iso-propyloxazolidin-2-ones ensures that the stereodirecting effect of its 4-iso-propyl-5,5-dimethyl functional group affords superior levels of facial selectivity normally associated with enolates derived from N-acyl-4-tert-butylox-azolidin-2-ones. |
| first_indexed | 2024-03-07T06:41:54Z |
| format | Journal article |
| id | oxford-uuid:f992e066-709c-4cd1-806e-1623e90c1fb2 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:41:54Z |
| publishDate | 2000 |
| record_format | dspace |
| spelling | oxford-uuid:f992e066-709c-4cd1-806e-1623e90c1fb22022-03-27T12:58:56ZConformational control in the SuperQuat chiral auxiliary 5,5-dimethyl-4-iso-propyloxazolidin-2-one induces the iso-propyl group to mimic a tert-butyl groupJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f992e066-709c-4cd1-806e-1623e90c1fb2EnglishSymplectic Elements at Oxford2000Bull, SDavies, SKey, MSNicholson, RSavory, E1H NMR nOe spectroscopic studies reveal that conformational control in the enolates of N-acyl-5,5-dimethyl-4-iso-propyloxazolidin-2-ones ensures that the stereodirecting effect of its 4-iso-propyl-5,5-dimethyl functional group affords superior levels of facial selectivity normally associated with enolates derived from N-acyl-4-tert-butylox-azolidin-2-ones. |
| spellingShingle | Bull, S Davies, S Key, MS Nicholson, R Savory, E Conformational control in the SuperQuat chiral auxiliary 5,5-dimethyl-4-iso-propyloxazolidin-2-one induces the iso-propyl group to mimic a tert-butyl group |
| title | Conformational control in the SuperQuat chiral auxiliary 5,5-dimethyl-4-iso-propyloxazolidin-2-one induces the iso-propyl group to mimic a tert-butyl group |
| title_full | Conformational control in the SuperQuat chiral auxiliary 5,5-dimethyl-4-iso-propyloxazolidin-2-one induces the iso-propyl group to mimic a tert-butyl group |
| title_fullStr | Conformational control in the SuperQuat chiral auxiliary 5,5-dimethyl-4-iso-propyloxazolidin-2-one induces the iso-propyl group to mimic a tert-butyl group |
| title_full_unstemmed | Conformational control in the SuperQuat chiral auxiliary 5,5-dimethyl-4-iso-propyloxazolidin-2-one induces the iso-propyl group to mimic a tert-butyl group |
| title_short | Conformational control in the SuperQuat chiral auxiliary 5,5-dimethyl-4-iso-propyloxazolidin-2-one induces the iso-propyl group to mimic a tert-butyl group |
| title_sort | conformational control in the superquat chiral auxiliary 5 5 dimethyl 4 iso propyloxazolidin 2 one induces the iso propyl group to mimic a tert butyl group |
| work_keys_str_mv | AT bulls conformationalcontrolinthesuperquatchiralauxiliary55dimethyl4isopropyloxazolidin2oneinducestheisopropylgrouptomimicatertbutylgroup AT daviess conformationalcontrolinthesuperquatchiralauxiliary55dimethyl4isopropyloxazolidin2oneinducestheisopropylgrouptomimicatertbutylgroup AT keyms conformationalcontrolinthesuperquatchiralauxiliary55dimethyl4isopropyloxazolidin2oneinducestheisopropylgrouptomimicatertbutylgroup AT nicholsonr conformationalcontrolinthesuperquatchiralauxiliary55dimethyl4isopropyloxazolidin2oneinducestheisopropylgrouptomimicatertbutylgroup AT savorye conformationalcontrolinthesuperquatchiralauxiliary55dimethyl4isopropyloxazolidin2oneinducestheisopropylgrouptomimicatertbutylgroup |