Application of the chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh(3))] to the stereoselective formation of 4-substituted-1,4-dihydronicotinoyl complexes

Application of the chiral auxiliary [(eta(5)-C5H5)Fe(CO)(PPh(3))] to the stereoselective formation of 4-substituted-1,4-dihydronicotinoyl complexes

In solution regio-and stereoselective additions of nucleophiles to (RS)-[(η5-C5H5)Fe(CO) (PPh3)CO-3-pyridyl] (1) occur at C-4 to give the corresponding nitrogen-stabilised anions. Subsequent quenching of these anions by a proton, a chloroformate or dimethyl sulfate gives the corresponding 1,4-dihydr...

Detaylı Bibliyografya
Asıl Yazarlar:	Beckett, R, Burgess, V, Davies, S, Krippner, G, Sutton, K, Whittaker, M
Materyal Türü:	Journal article
Dil:	English
Baskı/Yayın Bilgisi:	1996

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