CrCpTp: a high-spin Cr(II) sandwich complex with a large structural distortion.

CrCpTp: a high-spin Cr(II) sandwich complex with a large structural distortion.

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CrCpTp was synthesized from the reaction of [CrCpCl](2) and KTp. Magnetic measurements indicate it to have a high-spin (S = 2) electronic configuration from 5 to 300 K. A single-crystal X-ray study reveals bond lengths typical for a high-spin configuration and a pronounced Jahn-Teller distortion. Th...

書誌詳細
主要な著者:	Brunker, T, Green, J, O'Hare, D
フォーマット:	Journal article
言語:	English
出版事項:	2002

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