Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions.
X-ray powder diffraction and magnetic susceptibility measurements show that Ag(pyz)(2)(S(2)O(8)) consists of 2D square nets of Ag(2+) ions resulting from the corner-sharing of axially elongated AgN(4)O(2) octahedra and exhibits characteristic 2D antiferromagnetism. Nevertheless, mu(+)SR measurements...
Main Authors: | , , , , , , , , , , , , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2009
|
_version_ | 1797105390455881728 |
---|---|
author | Manson, J Stone, K Southerland, H Lancaster, T Steele, A Blundell, S Pratt, F Baker, P McDonald, R Sengupta, P Singleton, J Goddard, P Lee, C Whangbo, M Warter, M Mielke, C Stephens, P |
author_facet | Manson, J Stone, K Southerland, H Lancaster, T Steele, A Blundell, S Pratt, F Baker, P McDonald, R Sengupta, P Singleton, J Goddard, P Lee, C Whangbo, M Warter, M Mielke, C Stephens, P |
author_sort | Manson, J |
collection | OXFORD |
description | X-ray powder diffraction and magnetic susceptibility measurements show that Ag(pyz)(2)(S(2)O(8)) consists of 2D square nets of Ag(2+) ions resulting from the corner-sharing of axially elongated AgN(4)O(2) octahedra and exhibits characteristic 2D antiferromagnetism. Nevertheless, mu(+)SR measurements indicate that Ag(pyz)(2)(S(2)O(8)) undergoes 3D magnetic ordering below 7.8(3) K. |
first_indexed | 2024-03-07T06:46:52Z |
format | Journal article |
id | oxford-uuid:fb235ff8-b7cc-4ac8-bcc1-8950fbbe4dea |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T06:46:52Z |
publishDate | 2009 |
record_format | dspace |
spelling | oxford-uuid:fb235ff8-b7cc-4ac8-bcc1-8950fbbe4dea2022-03-27T13:11:36ZCharacterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fb235ff8-b7cc-4ac8-bcc1-8950fbbe4deaEnglishSymplectic Elements at Oxford2009Manson, JStone, KSoutherland, HLancaster, TSteele, ABlundell, SPratt, FBaker, PMcDonald, RSengupta, PSingleton, JGoddard, PLee, CWhangbo, MWarter, MMielke, CStephens, PX-ray powder diffraction and magnetic susceptibility measurements show that Ag(pyz)(2)(S(2)O(8)) consists of 2D square nets of Ag(2+) ions resulting from the corner-sharing of axially elongated AgN(4)O(2) octahedra and exhibits characteristic 2D antiferromagnetism. Nevertheless, mu(+)SR measurements indicate that Ag(pyz)(2)(S(2)O(8)) undergoes 3D magnetic ordering below 7.8(3) K. |
spellingShingle | Manson, J Stone, K Southerland, H Lancaster, T Steele, A Blundell, S Pratt, F Baker, P McDonald, R Sengupta, P Singleton, J Goddard, P Lee, C Whangbo, M Warter, M Mielke, C Stephens, P Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions. |
title | Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions. |
title_full | Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions. |
title_fullStr | Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions. |
title_full_unstemmed | Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions. |
title_short | Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions. |
title_sort | characterization of the antiferromagnetism in ag pyz 2 s2o8 pyz pyrazine with a two dimensional square lattice of ag2 ions |
work_keys_str_mv | AT mansonj characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT stonek characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT southerlandh characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT lancastert characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT steelea characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT blundells characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT prattf characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT bakerp characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT mcdonaldr characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT senguptap characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT singletonj characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT goddardp characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT leec characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT whangbom characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT warterm characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT mielkec characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions AT stephensp characterizationoftheantiferromagnetisminagpyz2s2o8pyzpyrazinewithatwodimensionalsquarelatticeofag2ions |