A comparison of the Still-Gennari and Ando HWE-methodologies with alpha,beta-unsaturated aldehydes; unexpected results with stannyl substituted systems

Still-Gennari reactions have been carried out on a range of E- and Z-3-substituted propenals. In all cases, with the exception of Z-3-stannyl systems, good Z-stereoselectivity was observed. By contrast, the Ando procedure gives reasonable Z-stereoselectivity with all systems studied, including those...

সম্পূর্ণ বিবরণ

গ্রন্থ-পঞ্জীর বিবরন
প্রধান লেখক: Franci, X, Martina, S, McGrady, J, Webb, MR, Donald, C, Taylor, R
বিন্যাস: Journal article
ভাষা:English
প্রকাশিত: 2003
বিবরন
সংক্ষিপ্ত:Still-Gennari reactions have been carried out on a range of E- and Z-3-substituted propenals. In all cases, with the exception of Z-3-stannyl systems, good Z-stereoselectivity was observed. By contrast, the Ando procedure gives reasonable Z-stereoselectivity with all systems studied, including those with a cis-disposed stannyl substituent. © 2003 Elsevier Ltd. All rights reserved.