Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates
The palladium-catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H-phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phosphonates in moderate to good yields and with exc...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2014
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| _version_ | 1797105553526226944 |
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| author | Candy, M Rousseaux, S Roman, A Szymczyk, M Kafarski, P Leclerc, E Vrancken, E Campagne, J |
| author_facet | Candy, M Rousseaux, S Roman, A Szymczyk, M Kafarski, P Leclerc, E Vrancken, E Campagne, J |
| author_sort | Candy, M |
| collection | OXFORD |
| description | The palladium-catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H-phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phosphonates in moderate to good yields and with excellent levels of regioselectivity. Hydrophosphonylations with internal, disubstituted and/or unactivated alkenes are also reported. © 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| first_indexed | 2024-03-07T06:49:00Z |
| format | Journal article |
| id | oxford-uuid:fbddbe63-65cf-4cef-ba5e-c6ccdd1b9ae8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:49:00Z |
| publishDate | 2014 |
| record_format | dspace |
| spelling | oxford-uuid:fbddbe63-65cf-4cef-ba5e-c6ccdd1b9ae82022-03-27T13:16:48ZPalladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-PhosphonatesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fbddbe63-65cf-4cef-ba5e-c6ccdd1b9ae8EnglishSymplectic Elements at Oxford2014Candy, MRousseaux, SRoman, ASzymczyk, MKafarski, PLeclerc, EVrancken, ECampagne, JThe palladium-catalyzed hydrophosphonylation of alkenes with previously unreactive acyclic dialkyl H-phosphonates has been developed. A catalyst system based on palladium/DavePhos or palladium/SPhos enables the transformation of various alkenes to phosphonates in moderate to good yields and with excellent levels of regioselectivity. Hydrophosphonylations with internal, disubstituted and/or unactivated alkenes are also reported. © 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| spellingShingle | Candy, M Rousseaux, S Roman, A Szymczyk, M Kafarski, P Leclerc, E Vrancken, E Campagne, J Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates |
| title | Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates |
| title_full | Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates |
| title_fullStr | Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates |
| title_full_unstemmed | Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates |
| title_short | Palladium-Catalyzed Hydrophosphonylation of Alkenes with Dialkyl H-Phosphonates |
| title_sort | palladium catalyzed hydrophosphonylation of alkenes with dialkyl h phosphonates |
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