Non-stabilized nucleophiles in Cu-catalysed dynamic kinetic asymmetric allylic alkylation

Non-stabilized nucleophiles in Cu-catalysed dynamic kinetic asymmetric allylic alkylation

The development of new reactions forming asymmetric carbon–carbon bonds has enabled chemists to synthesize a broad range of important carbon-containing molecules, including pharmaceutical agents, fragrances and polymers. Most strategies to obtain enantiomerically enriched molecules rely on either ge...

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Bibliografiske detaljer
Main Authors:	You, H, Rideau, E, Sidera, M, Fletcher, S
Format:	Journal article
Udgivet:	Nature Publishing Group 2015

Lignende værker

Asymmetric cross-coupling of alkyl, alkenyl and (hetero)aryl nucleophiles with racemic allyl halides
af: Schafer, P, et al.
Udgivet: (2017)

Cu-catalyzed asymmetric addition of sp²-hybridized zirconium nucleophiles to racemic allyl bromides.
af: Sidera, M, et al.
Udgivet: (2015)

Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans
af: Emeline Rideau, et al.
Udgivet: (2015-12-01)

Cu-catalyzed asymmetric addition of sp2-hybridized zirconium nucleophiles to racemic allyl bromides
af: Sidera, M, et al.
Udgivet: (2015)

Rhodium-catalysed asymmetric allylic arylation of racemic halides with arylboronic acids
af: Sidera, M, et al.
Udgivet: (2015)

Mechanistic studies on a Cu-catalyzed asymmetric allylic al-kylation with cyclic racemic starting materials
af: Rideau, E, et al.
Udgivet: (2017)

Organozirconocene nucleophiles in Cu-catalysed asymmetric transformations: methodologies, applications to total synthesis and NMR mechanistic studies
af: Rideau, E
Udgivet: (2016)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
af: Schäfer, P, et al.
Udgivet: (2017)

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
af: Philipp Schäfer, et al.
Udgivet: (2017-06-01)

Correction: Author Correction: Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates
af: Philipp Schäfer, et al.
Udgivet: (2018-05-01)

Non-stabilized nucleophiles in cu-catalyzed asymmetric synthesis
af: You, H
Udgivet: (2016)

Studies into iridium-catalysed asymmetric allylic alkylation towards the total synthesis of a dolabellane
af: Jiang, L
Udgivet: (2016)

Linear allylic halides in metal-catalysed asymmetric substitutions
af: Mistry, N
Udgivet: (2018)

Heterocyclic Trost’s ligands. Synthesis and applications in asymmetric allylic alkylation
af: Denis Sinou, et al.
Udgivet: (2004-09-01)

Chalcogen-containing oxazolines in the palladium-catalyzed asymmetric allylic alkylation
af: Braga Antonio L., et al.
Udgivet: (2006-01-01)

Recent Advances on the Catalytic Asymmetric Allylic α‑Alkylation of Carbonyl Derivatives Using Free Allylic Alcohols
af: Diego A. Alonso, et al.
Udgivet: (2024-02-01)

Copper-catalysed asymmetric annulation of yne-allylic esters with amines to access axially chiral arylpyrroles
af: Chaochao Yao, et al.
Udgivet: (2024-08-01)

Palladium-catalyzed allylic alkylation of enamides and allylic acetates
af: Lim, Juan Mei
Udgivet: (2012)

The Allylic Alkylation of Ketone Enolates
af: Dr. Lukas Junk, et al.
Udgivet: (2020-09-01)

Triflimide-catalyzed allyl–allyl cross-coupling : a metal-free allylic alkylation
af: Ding, Feiqing, et al.
Udgivet: (2013)

Asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with α-fluoro-β-keto esters
af: Yan, Lin, et al.
Udgivet: (2013)

Chiral, air stable, and reliable Pd(0) precatalysts applicable to asymmetric allylic alkylation chemistry
af: Jingjun Huang, et al.
Udgivet: (2023-12-01)

Asymmetric allylic alkylation of Morita–Baylis–Hillman carbonates with α-fluoro-β-keto esters
af: Lin Yan, et al.
Udgivet: (2013-09-01)

Nucleophilic trifluoromethoxylation of alkyl halides without silver
af: Yan Li, et al.
Udgivet: (2020-02-01)

Manganese-catalysed C2 allylation and deuteration of indoles in water
af: Si Lok Ko, et al.
Udgivet: (2023-12-01)

Copper catalyzed asymmetric synthesis of chiral allylic esters.
af: Geurts, K, et al.
Udgivet: (2006)

Spiro-fused carbohydrate oxazoline ligands: Synthesis and application as enantio-discrimination agents in asymmetric allylic alkylation
af: Jochen Kraft, et al.
Udgivet: (2016-01-01)

Sugar esterification catalysed by alkylated trypsin in dimethylformamide
af: Ampon, K., et al.
Udgivet: (1991)

Substrate scope and stereocontrol in the Rh(II)-catalysed oxyamination of allylic carbamates
af: Unsworth, W, et al.
Udgivet: (2014)

Investigation of the Acid/Basic Sites of Zeolite Trough Some Catalysed Nucleophilic Reactions
af: Valentina Verdoliva, et al.
Udgivet: (2023-02-01)

Asymmetric α-C(sp 3)−H allylic alkylation of primary alkylamines by synergistic Ir/ketone catalysis
af: Jianyu Li, et al.
Udgivet: (2024-01-01)

Controlling absolute stereochemistry in hydrogen borrowing catalysed alkylation
af: Cheang, DMJ-Y
Udgivet: (2023)

Copper-catalysed alkylation of heterocyclic acceptors with organometallic reagents
af: Yafei Guo, et al.
Udgivet: (2020-05-01)

Alkaline-earth metal catalyzed dehydrative allylic alkylation
af: Xie, Peizhong, et al.
Udgivet: (2022)

Asymmetric synthesis of nortropanes via Rh-catalyzed allylic arylation
af: Zhang, Y, et al.
Udgivet: (2022)

Asymmetric electrophilic fluorocyclization with carbon nucleophiles.
af: Wolstenhulme, JR, et al.
Udgivet: (2013)

Selectivity Control in the Palladium-catalyzed Cross-coupling of Alkyl Nucleophiles
af: Olivier Baudoin
Udgivet: (2016-11-01)

Ligand-enabled Ni-catalysed enantioconvergent intermolecular Alkyl-Alkyl cross-coupling between distinct Alkyl halides
af: Wen-Tao Zhao, et al.
Udgivet: (2023-05-01)

Copper-catalysed asymmetric 1,4-conjugate addition of alkylzirconium compounds
af: Maksymowicz, R, et al.
Udgivet: (2012)

Dynamic kinetic resolution allows control of remote stereochemistry in asymmetric hydrogen borrowing alkylation
af: Cheang, DMJ, et al.
Udgivet: (2025)