Synthesis and reactivity of α‐cumyl bromodifluoromethanesulfenate: application to the radiosynthesis of [18F]arylSCF3
A highly reactive electrophilic bromodifluoromethylthiolating reagent, α‐cumyl bromodifluoro‐methanesulfenate 1, was prepared to allow for direct bromodifluoromethylthiolation of aryl boron reagents. This coupling reaction takes place under copper catalysis, and affords a large range of bromodifluor...
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| Príomhchruthaitheoirí: |
Wu, J,
Zhao, Q,
Wilson, TC,
Verhoog, S,
Gouverneur, V,
Lu, L,
Shen, Q |
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| Formáid: | Journal article
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| Teanga: | English |
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| Foilsithe / Cruthaithe: |
Wiley
2019
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