Synthesis and reactivity of α‐cumyl bromodifluoromethanesulfenate: application to the radiosynthesis of [18F]arylSCF3
A highly reactive electrophilic bromodifluoromethylthiolating reagent, α‐cumyl bromodifluoro‐methanesulfenate 1, was prepared to allow for direct bromodifluoromethylthiolation of aryl boron reagents. This coupling reaction takes place under copper catalysis, and affords a large range of bromodifluor...
Hlavní autoři: | Wu, J, Zhao, Q, Wilson, TC, Verhoog, S, Gouverneur, V, Lu, L, Shen, Q |
---|---|
Médium: | Journal article |
Jazyk: | English |
Vydáno: |
Wiley
2019
|
Podobné jednotky
-
Radiosynthesis of [18F]ArylSCF2H using aryl boronic acids, S-(chlorofluoromethyl)benzenesulfonothioate and [18F]fluoride
Autor: Zhao, Q, a další
Vydáno: (2020) -
Convergent 18F Radiosynthesis
Autor: Gouverneur, V, a další
Vydáno: (2012) -
Manual and automated Cu-mediated radiosynthesis of the PARP inhibitor [18F]olaparib
Autor: Guibbal, F, a další
Vydáno: (2020) -
Copper-mediated radiosynthesis of [18F]rucaparib
Autor: Chen, Z, a další
Vydáno: (2021) -
Optimizing the radiosynthesis of 6-[F-18]FDOPA using [F-18]Selectfluor
Autor: Forsback, S, a další
Vydáno: (2013)