Synthesis and reactivity of α‐cumyl bromodifluoromethanesulfenate: application to the radiosynthesis of [18F]arylSCF3
A highly reactive electrophilic bromodifluoromethylthiolating reagent, α‐cumyl bromodifluoro‐methanesulfenate 1, was prepared to allow for direct bromodifluoromethylthiolation of aryl boron reagents. This coupling reaction takes place under copper catalysis, and affords a large range of bromodifluor...
Κύριοι συγγραφείς: | Wu, J, Zhao, Q, Wilson, TC, Verhoog, S, Gouverneur, V, Lu, L, Shen, Q |
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Μορφή: | Journal article |
Γλώσσα: | English |
Έκδοση: |
Wiley
2019
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