Synthesis and reactivity of α‐cumyl bromodifluoromethanesulfenate: application to the radiosynthesis of [18F]arylSCF3

A highly reactive electrophilic bromodifluoromethylthiolating reagent, α‐cumyl bromodifluoro‐methanesulfenate 1, was prepared to allow for direct bromodifluoromethylthiolation of aryl boron reagents. This coupling reaction takes place under copper catalysis, and affords a large range of bromodifluor...

وصف كامل

التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Wu, J, Zhao, Q, Wilson, TC, Verhoog, S, Gouverneur, V, Lu, L, Shen, Q
التنسيق: Journal article
اللغة:English
منشور في: Wiley 2019