Photocatalytic CO2 reduction and environmental remediation using mineralization of toxic metal cations products

<p>Exploring a sustainable route for the efficient treating/recycling of heavy metal (like Ni<sup>2+</sup>, Cd<sup>2+</sup>, Cu<sup>2+</sup>) contamination of water is highly desirable both from the environment and resource view. Herein, we reported the scal...

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Główni autorzy: Lai, T, Wang, J, Xiong, W, Wang, H, Yang, M, Li, T, Kong, X, Zou, X, Zhao, Y, O'Hare, D, Song, Y-F
Format: Journal article
Język:English
Wydane: Elsevier 2022
Opis
Streszczenie:<p>Exploring a sustainable route for the efficient treating/recycling of heavy metal (like Ni<sup>2+</sup>, Cd<sup>2+</sup>, Cu<sup>2+</sup>) contamination of water is highly desirable both from the environment and resource view. Herein, we reported the scale-up synthesis of monolayer magnesium-aluminium layered double hydroxide (m-MgAl-LDH) nanosheets, which showed exceptional ability to mineralize Ni<sup>2+</sup>, Cd<sup>2+</sup>&nbsp;and Cu<sup>2+</sup>&nbsp;rapidly and efficiently. Furthermore, m-MgAl-LDH can purify 1&nbsp;ppm Cu<sup>2+</sup>, Ni<sup>2+</sup>&nbsp;and Cd<sup>2+</sup>&nbsp;to safe levels. The sorption sites of heavy metal ions were revealed. Ni<sup>2+</sup>&nbsp;and Cd<sup>2+</sup>&nbsp;substitute for the Mg<sup>2+</sup>&nbsp;sites within the MgAl-LDH layers, while Cu<sup>2+</sup>&nbsp;ions anchor on the surface of MgAl-LDH with high dispersion. The mineralized products from Ni<sup>2+</sup>&nbsp;and Cu<sup>2+</sup>&nbsp;cations further showed excellent performance in visible-light-induced photocatalytic reduction of CO<sub>2</sub>&nbsp;and removal of anions (like PO<sub>4</sub><sup>3-</sup>&nbsp;and toxic AsO<sub>2</sub><sup>-</sup>&nbsp;ions) efficiently, providing an alternative for the mitigation of energy and resource crisis.</p>