FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)]
The novel three-vertex metallaborane [Ru(η-C5Me 5)(PMe3)(η2-B2H7)] (1) has been synthesised by reaction of [Ru(η-C5Me 5)(PMe3)Cl2] with NaBH4; homologation is also observed in the reaction of [Mo(η-C5H 5)2H2] with BH3·THF, which forms [Mo(η-C5H5)2H(η2- B2H5)] (2); X-ray crystal structures of compoun...
| Main Authors: | , , , , , , , |
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| Format: | Journal article |
| Jezik: | English |
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1988
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| _version_ | 1826306824578531328 |
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| author | Grebenik, P Green, M Kelland, M Leach, J Mountford, P Stringer, G Walker, N Wong, L |
| author_facet | Grebenik, P Green, M Kelland, M Leach, J Mountford, P Stringer, G Walker, N Wong, L |
| author_sort | Grebenik, P |
| collection | OXFORD |
| description | The novel three-vertex metallaborane [Ru(η-C5Me 5)(PMe3)(η2-B2H7)] (1) has been synthesised by reaction of [Ru(η-C5Me 5)(PMe3)Cl2] with NaBH4; homologation is also observed in the reaction of [Mo(η-C5H 5)2H2] with BH3·THF, which forms [Mo(η-C5H5)2H(η2- B2H5)] (2); X-ray crystal structures of compounds (1) and (2) are reported. |
| first_indexed | 2024-03-07T06:53:45Z |
| format | Journal article |
| id | oxford-uuid:fd6b7d77-8e90-4e24-a396-0fb3036beac9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:53:45Z |
| publishDate | 1988 |
| record_format | dspace |
| spelling | oxford-uuid:fd6b7d77-8e90-4e24-a396-0fb3036beac92022-03-27T13:28:39ZFORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)]Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fd6b7d77-8e90-4e24-a396-0fb3036beac9EnglishSymplectic Elements at Oxford1988Grebenik, PGreen, MKelland, MLeach, JMountford, PStringer, GWalker, NWong, LThe novel three-vertex metallaborane [Ru(η-C5Me 5)(PMe3)(η2-B2H7)] (1) has been synthesised by reaction of [Ru(η-C5Me 5)(PMe3)Cl2] with NaBH4; homologation is also observed in the reaction of [Mo(η-C5H 5)2H2] with BH3·THF, which forms [Mo(η-C5H5)2H(η2- B2H5)] (2); X-ray crystal structures of compounds (1) and (2) are reported. |
| spellingShingle | Grebenik, P Green, M Kelland, M Leach, J Mountford, P Stringer, G Walker, N Wong, L FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)] |
| title | FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)] |
| title_full | FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)] |
| title_fullStr | FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)] |
| title_full_unstemmed | FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)] |
| title_short | FORMATION OF 3-VERTEX METALLABORANES FROM MONOBORANE PRECURSORS - X-RAY CRYSTAL-STRUCTURES OF THE MOLYBDENUM AND RUTHENIUM COMPLEXES [MO(ETA-C5H5)2H(ETA-2-B2H5)] AND [RU(ETA-C5ME5)(PME3)(ETA-2-B2H7)] |
| title_sort | formation of 3 vertex metallaboranes from monoborane precursors x ray crystal structures of the molybdenum and ruthenium complexes mo eta c5h5 2h eta 2 b2h5 and ru eta c5me5 pme3 eta 2 b2h7 |
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