Single-molecule magnet properties of a monometallic dysprosium pentalene complex
The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1. Whilst the [Cp*]- ligand in 1Dy provides a strong axial crystal field, the overall axiality of this syste...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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Royal Society of Chemistry
2018
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| _version_ | 1797105907584204800 |
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| author | Kilpatrick, AFR Guo, F-S Day, BM Mansikkamäki, A Layfield, RA Cloke, FGN |
| author_facet | Kilpatrick, AFR Guo, F-S Day, BM Mansikkamäki, A Layfield, RA Cloke, FGN |
| author_sort | Kilpatrick, AFR |
| collection | OXFORD |
| description | The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1. Whilst the [Cp*]- ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2- ligand. |
| first_indexed | 2024-03-07T06:54:04Z |
| format | Journal article |
| id | oxford-uuid:fd8694ac-494f-4829-b8a2-f0e585f5c843 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:54:04Z |
| publishDate | 2018 |
| publisher | Royal Society of Chemistry |
| record_format | dspace |
| spelling | oxford-uuid:fd8694ac-494f-4829-b8a2-f0e585f5c8432022-03-27T13:29:26ZSingle-molecule magnet properties of a monometallic dysprosium pentalene complexJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fd8694ac-494f-4829-b8a2-f0e585f5c843EnglishSymplectic Elements at OxfordRoyal Society of Chemistry2018Kilpatrick, AFRGuo, F-SDay, BMMansikkamäki, ALayfield, RACloke, FGNThe pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1. Whilst the [Cp*]- ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2- ligand. |
| spellingShingle | Kilpatrick, AFR Guo, F-S Day, BM Mansikkamäki, A Layfield, RA Cloke, FGN Single-molecule magnet properties of a monometallic dysprosium pentalene complex |
| title | Single-molecule magnet properties of a monometallic dysprosium pentalene complex |
| title_full | Single-molecule magnet properties of a monometallic dysprosium pentalene complex |
| title_fullStr | Single-molecule magnet properties of a monometallic dysprosium pentalene complex |
| title_full_unstemmed | Single-molecule magnet properties of a monometallic dysprosium pentalene complex |
| title_short | Single-molecule magnet properties of a monometallic dysprosium pentalene complex |
| title_sort | single molecule magnet properties of a monometallic dysprosium pentalene complex |
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