Single-molecule magnet properties of a monometallic dysprosium pentalene complex

The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2-) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm-1. Whilst the [Cp*]- ligand in 1Dy provides a strong axial crystal field, the overall axiality of this syste...

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Bibliographic Details
Main Authors: Kilpatrick, AFR, Guo, F-S, Day, BM, Mansikkamäki, A, Layfield, RA, Cloke, FGN
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2018

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