High Purity GaAs Nanowires Free of Planar Defects: Growth and Characterization

We investigate how to tailor the structural, crystallographic and optical properties of GaAs nanowires. Nanowires were grown by Au nanoparticle-catalyzed metalorganic chemical vapor deposition. A high arsine flow rate, that is, a high ratio of group V to group III precursors, imparts significant adv...

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Autori principali: Joyce, H, Gao, Q, Tan, H, Jagadish, C, Kim, Y, Fickenscher, M, Perera, S, Hoang, T, Smith, L, Jackson, H, Yarrison-Rice, J, Zhang, X, Zou, J
Natura: Journal article
Lingua:English
Pubblicazione: 2008
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author Joyce, H
Gao, Q
Tan, H
Jagadish, C
Kim, Y
Fickenscher, M
Perera, S
Hoang, T
Smith, L
Jackson, H
Yarrison-Rice, J
Zhang, X
Zou, J
author_facet Joyce, H
Gao, Q
Tan, H
Jagadish, C
Kim, Y
Fickenscher, M
Perera, S
Hoang, T
Smith, L
Jackson, H
Yarrison-Rice, J
Zhang, X
Zou, J
author_sort Joyce, H
collection OXFORD
description We investigate how to tailor the structural, crystallographic and optical properties of GaAs nanowires. Nanowires were grown by Au nanoparticle-catalyzed metalorganic chemical vapor deposition. A high arsine flow rate, that is, a high ratio of group V to group III precursors, imparts significant advantages. It dramatically reduces planar crystallographic defects and reduces intrinsic carbon dopant incorporation. Increasing V/III ratio further, however, instigates nanowire kinking and increases nanowire tapering. By choosing an intermediate V/III ratio we achieve uniform, vertically aligned GaAs nanowires, free of planar crystallographic defects, with excellent optical properties and high purity. These findings will greatly assist the development of future GaAs nanowire-based electronic and optoelectronic devices, and are expected to be more broadly relevant to the rational synthesis of other III-V nanowires. © 2008 WILEY-VCH Verlag GmbH and Co. KGaA.
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spelling oxford-uuid:fe0082f9-1d4e-4d48-ada7-55b6675b9da12022-03-27T13:32:57ZHigh Purity GaAs Nanowires Free of Planar Defects: Growth and CharacterizationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fe0082f9-1d4e-4d48-ada7-55b6675b9da1EnglishSymplectic Elements at Oxford2008Joyce, HGao, QTan, HJagadish, CKim, YFickenscher, MPerera, SHoang, TSmith, LJackson, HYarrison-Rice, JZhang, XZou, JWe investigate how to tailor the structural, crystallographic and optical properties of GaAs nanowires. Nanowires were grown by Au nanoparticle-catalyzed metalorganic chemical vapor deposition. A high arsine flow rate, that is, a high ratio of group V to group III precursors, imparts significant advantages. It dramatically reduces planar crystallographic defects and reduces intrinsic carbon dopant incorporation. Increasing V/III ratio further, however, instigates nanowire kinking and increases nanowire tapering. By choosing an intermediate V/III ratio we achieve uniform, vertically aligned GaAs nanowires, free of planar crystallographic defects, with excellent optical properties and high purity. These findings will greatly assist the development of future GaAs nanowire-based electronic and optoelectronic devices, and are expected to be more broadly relevant to the rational synthesis of other III-V nanowires. © 2008 WILEY-VCH Verlag GmbH and Co. KGaA.
spellingShingle Joyce, H
Gao, Q
Tan, H
Jagadish, C
Kim, Y
Fickenscher, M
Perera, S
Hoang, T
Smith, L
Jackson, H
Yarrison-Rice, J
Zhang, X
Zou, J
High Purity GaAs Nanowires Free of Planar Defects: Growth and Characterization
title High Purity GaAs Nanowires Free of Planar Defects: Growth and Characterization
title_full High Purity GaAs Nanowires Free of Planar Defects: Growth and Characterization
title_fullStr High Purity GaAs Nanowires Free of Planar Defects: Growth and Characterization
title_full_unstemmed High Purity GaAs Nanowires Free of Planar Defects: Growth and Characterization
title_short High Purity GaAs Nanowires Free of Planar Defects: Growth and Characterization
title_sort high purity gaas nanowires free of planar defects growth and characterization
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