Electrochemical detection of single micelles through 'nano-impacts'
A new class of 'soft' particles, micelles, is detected electrochemically via 'nano-impacts' for the first time. Short, sharp bursts of current are used to indicate the electrical contact of a single CTAB (cetyltrimethylammonium bromide) micelle with an electrode via the oxidation...
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Format: | Journal article |
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Royal Society of Chemistry
2015
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author | Toh, H Compton, R |
author_facet | Toh, H Compton, R |
author_sort | Toh, H |
collection | OXFORD |
description | A new class of 'soft' particles, micelles, is detected electrochemically via 'nano-impacts' for the first time. Short, sharp bursts of current are used to indicate the electrical contact of a single CTAB (cetyltrimethylammonium bromide) micelle with an electrode via the oxidation of the bromide content. The variation in CTAB concentration for such 'nano-impact' experiments shows that a significant number of 'spikes' are observed above the CMC (critical micelle concentration) and this is attributed to the formation of micelles. A comparison with dynamic light scattering is also reported. |
first_indexed | 2024-03-07T06:56:13Z |
format | Journal article |
id | oxford-uuid:fe3bdabf-829d-47f4-806d-ada46fd50cb7 |
institution | University of Oxford |
last_indexed | 2024-03-07T06:56:13Z |
publishDate | 2015 |
publisher | Royal Society of Chemistry |
record_format | dspace |
spelling | oxford-uuid:fe3bdabf-829d-47f4-806d-ada46fd50cb72022-03-27T13:34:46ZElectrochemical detection of single micelles through 'nano-impacts'Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fe3bdabf-829d-47f4-806d-ada46fd50cb7Symplectic Elements at OxfordRoyal Society of Chemistry2015Toh, HCompton, RA new class of 'soft' particles, micelles, is detected electrochemically via 'nano-impacts' for the first time. Short, sharp bursts of current are used to indicate the electrical contact of a single CTAB (cetyltrimethylammonium bromide) micelle with an electrode via the oxidation of the bromide content. The variation in CTAB concentration for such 'nano-impact' experiments shows that a significant number of 'spikes' are observed above the CMC (critical micelle concentration) and this is attributed to the formation of micelles. A comparison with dynamic light scattering is also reported. |
spellingShingle | Toh, H Compton, R Electrochemical detection of single micelles through 'nano-impacts' |
title | Electrochemical detection of single micelles through 'nano-impacts' |
title_full | Electrochemical detection of single micelles through 'nano-impacts' |
title_fullStr | Electrochemical detection of single micelles through 'nano-impacts' |
title_full_unstemmed | Electrochemical detection of single micelles through 'nano-impacts' |
title_short | Electrochemical detection of single micelles through 'nano-impacts' |
title_sort | electrochemical detection of single micelles through nano impacts |
work_keys_str_mv | AT tohh electrochemicaldetectionofsinglemicellesthroughnanoimpacts AT comptonr electrochemicaldetectionofsinglemicellesthroughnanoimpacts |