Electrochemical detection of single micelles through 'nano-impacts'

A new class of 'soft' particles, micelles, is detected electrochemically via 'nano-impacts' for the first time. Short, sharp bursts of current are used to indicate the electrical contact of a single CTAB (cetyltrimethylammonium bromide) micelle with an electrode via the oxidation...

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Main Authors: Toh, H, Compton, R
Format: Journal article
Published: Royal Society of Chemistry 2015
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author Toh, H
Compton, R
author_facet Toh, H
Compton, R
author_sort Toh, H
collection OXFORD
description A new class of 'soft' particles, micelles, is detected electrochemically via 'nano-impacts' for the first time. Short, sharp bursts of current are used to indicate the electrical contact of a single CTAB (cetyltrimethylammonium bromide) micelle with an electrode via the oxidation of the bromide content. The variation in CTAB concentration for such 'nano-impact' experiments shows that a significant number of 'spikes' are observed above the CMC (critical micelle concentration) and this is attributed to the formation of micelles. A comparison with dynamic light scattering is also reported.
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spelling oxford-uuid:fe3bdabf-829d-47f4-806d-ada46fd50cb72022-03-27T13:34:46ZElectrochemical detection of single micelles through 'nano-impacts'Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fe3bdabf-829d-47f4-806d-ada46fd50cb7Symplectic Elements at OxfordRoyal Society of Chemistry2015Toh, HCompton, RA new class of 'soft' particles, micelles, is detected electrochemically via 'nano-impacts' for the first time. Short, sharp bursts of current are used to indicate the electrical contact of a single CTAB (cetyltrimethylammonium bromide) micelle with an electrode via the oxidation of the bromide content. The variation in CTAB concentration for such 'nano-impact' experiments shows that a significant number of 'spikes' are observed above the CMC (critical micelle concentration) and this is attributed to the formation of micelles. A comparison with dynamic light scattering is also reported.
spellingShingle Toh, H
Compton, R
Electrochemical detection of single micelles through 'nano-impacts'
title Electrochemical detection of single micelles through 'nano-impacts'
title_full Electrochemical detection of single micelles through 'nano-impacts'
title_fullStr Electrochemical detection of single micelles through 'nano-impacts'
title_full_unstemmed Electrochemical detection of single micelles through 'nano-impacts'
title_short Electrochemical detection of single micelles through 'nano-impacts'
title_sort electrochemical detection of single micelles through nano impacts
work_keys_str_mv AT tohh electrochemicaldetectionofsinglemicellesthroughnanoimpacts
AT comptonr electrochemicaldetectionofsinglemicellesthroughnanoimpacts