Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy
The nature of electronic states at the Fermi energy in metallic β-PbO2 has been identified by hard x-ray photoemission spectroscopy (HXPS) combined with x-ray emission spectroscopy and density-functional theory calculations. Pb 6s states are strongly enhanced in HXP spectra, allowing us to locate th...
| Váldodahkkit: | , , , , , , , , , , , , , , |
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| Materiálatiipa: | Journal article |
| Giella: | English |
| Almmustuhtton: |
American Physical Society
2007
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| Fáttát: |
| _version_ | 1826306998770073600 |
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| author | Payne, D Egdell, R Paolicelli, G Offi, F Panaccione, G Lacovig, P Monaco, G Vanko, G Walsh, A Watson, G Guo, J Beamson, G Glans, P Learmonth, T Smith, K |
| author_facet | Payne, D Egdell, R Paolicelli, G Offi, F Panaccione, G Lacovig, P Monaco, G Vanko, G Walsh, A Watson, G Guo, J Beamson, G Glans, P Learmonth, T Smith, K |
| author_sort | Payne, D |
| collection | OXFORD |
| description | The nature of electronic states at the Fermi energy in metallic β-PbO2 has been identified by hard x-ray photoemission spectroscopy (HXPS) combined with x-ray emission spectroscopy and density-functional theory calculations. Pb 6s states are strongly enhanced in HXP spectra, allowing us to locate the Fermi level above the top of the valence band. The occupied conduction-band states have significant Pb 6s character, although the major 6s contribution to the density of states is found 9 eV below the Fermi energy. The enormous potential of HXPS for the study of s states in oxides is emphasized. |
| first_indexed | 2024-03-07T06:56:25Z |
| format | Journal article |
| id | oxford-uuid:fe48e3d9-60b7-4390-8231-2912306baa9a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:56:25Z |
| publishDate | 2007 |
| publisher | American Physical Society |
| record_format | dspace |
| spelling | oxford-uuid:fe48e3d9-60b7-4390-8231-2912306baa9a2022-03-27T13:35:18ZNature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopyJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fe48e3d9-60b7-4390-8231-2912306baa9aPhysicsChemistry & allied sciencesInorganic chemistryEnglishOxford University Research Archive - ValetAmerican Physical Society2007Payne, DEgdell, RPaolicelli, GOffi, FPanaccione, GLacovig, PMonaco, GVanko, GWalsh, AWatson, GGuo, JBeamson, GGlans, PLearmonth, TSmith, KThe nature of electronic states at the Fermi energy in metallic β-PbO2 has been identified by hard x-ray photoemission spectroscopy (HXPS) combined with x-ray emission spectroscopy and density-functional theory calculations. Pb 6s states are strongly enhanced in HXP spectra, allowing us to locate the Fermi level above the top of the valence band. The occupied conduction-band states have significant Pb 6s character, although the major 6s contribution to the density of states is found 9 eV below the Fermi energy. The enormous potential of HXPS for the study of s states in oxides is emphasized. |
| spellingShingle | Physics Chemistry & allied sciences Inorganic chemistry Payne, D Egdell, R Paolicelli, G Offi, F Panaccione, G Lacovig, P Monaco, G Vanko, G Walsh, A Watson, G Guo, J Beamson, G Glans, P Learmonth, T Smith, K Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy |
| title | Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy |
| title_full | Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy |
| title_fullStr | Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy |
| title_full_unstemmed | Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy |
| title_short | Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy |
| title_sort | nature of electronic states at the fermi level of metallic beta pbo2 revealed by hard x ray photoemission spectroscopy |
| topic | Physics Chemistry & allied sciences Inorganic chemistry |
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