Linking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2)
Similar In(μ-Br) 2M bridging motifs are found in the crystal structures of the diindium and mixed lithium/indium species [{(η 5-C 5H 5)Fe(CO) 2} 2InBr] 2 (1) and [(η 5-C 5H 5)Fe(CO) 2]2In(μ-Br) 2Li(OEt 2) 2 (2). The metric parameters for 1 are in close agreement with those found for the analogous ch...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2007
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| _version_ | 1797106105861537792 |
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| author | Coombs, N Day, J Aldridge, S Coles, S Hursthouse, M |
| author_facet | Coombs, N Day, J Aldridge, S Coles, S Hursthouse, M |
| author_sort | Coombs, N |
| collection | OXFORD |
| description | Similar In(μ-Br) 2M bridging motifs are found in the crystal structures of the diindium and mixed lithium/indium species [{(η 5-C 5H 5)Fe(CO) 2} 2InBr] 2 (1) and [(η 5-C 5H 5)Fe(CO) 2]2In(μ-Br) 2Li(OEt 2) 2 (2). The metric parameters for 1 are in close agreement with those found for the analogous chloride and iodide complexes, but differ from those found in monomelic [(η 5-C 5Me 5)Fe(CO) 2] 2InBr, on account of the four coordinate geometry at indium and the bridging nature of the bromide ligands. |
| first_indexed | 2024-03-07T06:56:59Z |
| format | Journal article |
| id | oxford-uuid:fe75887f-8261-4e63-a4de-bc7396c761dc |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:56:59Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:fe75887f-8261-4e63-a4de-bc7396c761dc2022-03-27T13:36:40ZLinking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2)Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:fe75887f-8261-4e63-a4de-bc7396c761dcEnglishSymplectic Elements at Oxford2007Coombs, NDay, JAldridge, SColes, SHursthouse, MSimilar In(μ-Br) 2M bridging motifs are found in the crystal structures of the diindium and mixed lithium/indium species [{(η 5-C 5H 5)Fe(CO) 2} 2InBr] 2 (1) and [(η 5-C 5H 5)Fe(CO) 2]2In(μ-Br) 2Li(OEt 2) 2 (2). The metric parameters for 1 are in close agreement with those found for the analogous chloride and iodide complexes, but differ from those found in monomelic [(η 5-C 5Me 5)Fe(CO) 2] 2InBr, on account of the four coordinate geometry at indium and the bridging nature of the bromide ligands. |
| spellingShingle | Coombs, N Day, J Aldridge, S Coles, S Hursthouse, M Linking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2) |
| title | Linking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2) |
| title_full | Linking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2) |
| title_fullStr | Linking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2) |
| title_full_unstemmed | Linking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2) |
| title_short | Linking of main group metals via bridging halide ligands: Structures of the bromo-indanediyl dimer [{(eta(5)-C5H5)Fe(CO)(2)}(2)InBr](2) and the related lithium bromide adduct [(eta(5)-C5H5)Fe(CO)(2)](2)In(mu-Br)(2)Li(OEt2)(2) |
| title_sort | linking of main group metals via bridging halide ligands structures of the bromo indanediyl dimer eta 5 c5h5 fe co 2 2 inbr 2 and the related lithium bromide adduct eta 5 c5h5 fe co 2 2 in mu br 2 li oet2 2 |
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