Intermolecular rhodium catalyzed hydroacylation of allenes: the regioselective synthesis of beta,gamma-unsaturated ketones
A variety of β-S-substituted aldehydes undergo efficient and regioselective rhodium catalyzed hydroacylation reactions with 1,3-disubstituted and 1,1,3-trisubstituted allenes, to deliver β,γ-unsaturated ketone products. Regioselectivites are controlled primarily by steric factors. The reactions are...
| Main Authors: | , , , , |
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| 格式: | Journal article |
| 语言: | English |
| 出版: |
2009
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