Mechanistic insights into stereoselective catalysis-the effects of counterions in a CuII-bissulfoximine-catalyzed Diels-Alder reaction.

The initial steps of an enantioselective Diels-Alder reaction catalyzed by a CuII-bissulfoximine complex were followed by EXAFS (EXAFS=extended X-ray absorption fine structure), EPR (EPR=electron paramagnetic resonance) spectroscopy (CW-EPR, FID-detected EPR, pulse ENDOR, HYSCORE; CW=continuous wave...

Ausführliche Beschreibung

Bibliographische Detailangaben
Hauptverfasser: Bolm, C, Martin, M, Gescheidt, G, Palivan, C, Stanoeva, T, Bertagnolli, H, Feth, M, Schweiger, A, Mitrikas, G, Harmer, J
Format: Journal article
Sprache:English
Veröffentlicht: 2007