Mechanistic insights into stereoselective catalysis-the effects of counterions in a CuII-bissulfoximine-catalyzed Diels-Alder reaction.

Mechanistic insights into stereoselective catalysis-the effects of counterions in a CuII-bissulfoximine-catalyzed Diels-Alder reaction.

The initial steps of an enantioselective Diels-Alder reaction catalyzed by a CuII-bissulfoximine complex were followed by EXAFS (EXAFS=extended X-ray absorption fine structure), EPR (EPR=electron paramagnetic resonance) spectroscopy (CW-EPR, FID-detected EPR, pulse ENDOR, HYSCORE; CW=continuous wave...

Full description

Bibliographic Details
Main Authors:	Bolm, C, Martin, M, Gescheidt, G, Palivan, C, Stanoeva, T, Bertagnolli, H, Feth, M, Schweiger, A, Mitrikas, G, Harmer, J
Format:	Journal article
Language:	English
Published:	2007

Similar Items

Spectroscopic investigations of bis(sulfoximine) copper(II) complexes and their relevance in asymmetric catalysis.
by: Bolm, C, et al.
Published: (2003)

Origins of stereoselectivity in the trans Diels-Alder paradigm.
by: Paton, R, et al.
Published: (2010)

Counterion-directed approach to the Diels-Alder paradigm: cascade synthesis of tricyclic fused cyclopropanes
by: Kiss, E, et al.
Published: (2016)

STEREOSELECTIVE DIELS-ALDER REACTIONS OF A NEW CHIRAL CARBAMOYLNITROSO COMPOUND
by: Gouverneur, V, et al.
Published: (1990)

Dynamic intermediates in the radical cation diels–alder cycloaddition: lifetime and suprafacial stereoselectivity
by: Tan, J, et al.
Published: (2018)

Control of the exo and endo pathways of the Diels-Alder reaction by antibody catalysis.
by: Gouverneur, V, et al.
Published: (1993)

Probing substituent effects in aryl-aryl interactions using stereoselective diels-alder cycloadditions
by: Wheeler, Steven E., et al.
Published: (2012)

Intramolecular Diels-Alder reactions of cycloalkenones: stereoselectivity, Lewis acid acceleration, and halogen substituent effects.
by: Pham, H, et al.
Published: (2014)

Asymmetric intramolecular Diels-Alder reactions
by: Essenfeld, Amy Pia
Published: (2005)

Tindak balas siklotambahan Diels-Alder /
by: 175536 Sim, Siaw Jiet
Published: (2001)

Synthetic studies of the intramolecular Diels-Alder reaction
by: Warmus, Joseph Scott Warmus
Published: (2005)

Stereochemical aspects of the intramolecular Diels-Alder reaction
by: Gillis, Herbert Russell
Published: (2005)

An intramolecular diels-alder (IMDA) approach to biaryls.
by: Ong, Michelle Jui Hsien.
Published: (2010)

Diels-Alder reactions of organotin acetylides and the chemistry of the adducts
by: Evnin, Anthony Basil
Published: (2017)

Rapid chemical ligation of oligonucleotides by the Diels-Alder reaction.
by: El-Sagheer, A, et al.
Published: (2011)

Synthesis of self-healing Diels-Alder cross-linked polymer
by: Tan, Yann Ming
Published: (2014)

Biocatalytic approaches to hetero-Diels-Alder adducts of carbonyl compounds.
by: Gouverneur, V, et al.
Published: (2005)

Fast and efficient chemical ligation of oligonucleotides using diels-alder reaction.
by: Cheong, Vee Vee.
Published: (2010)

ASYMMETRIC AMINATION OF CARBOXYLIC-ACIDS VIA A DIELS-ALDER STRATEGY
by: Gouverneur, V, et al.
Published: (1991)

Origins of regioselectivity of Diels-Alder reactions for the synthesis of bisanthraquinone antibiotic BE-43472B.
by: Hayden, A, et al.
Published: (2010)

Formal Diels-Alder reactions of chalcones and formylcyclopropanes catalyzed by chiral N-heterocyclic carbenes
by: Lv, Hui, et al.
Published: (2014)

EXO-SELECTIVE ACCELERATION OF AN INTERMOLECULAR DIELS-ALDER REACTION BY A TRIMERIC PORPHYRIN HOST
by: Walter, C, et al.
Published: (1993)

Aldolase class I antibody route to hetero Diels-Alder adducts of carbonyl compounds
by: Baker-Glenn, C, et al.
Published: (2003)

Synthesis and Diels–Alder Reactivity of 4-Fluoro-4-Methyl-4H-Pyrazoles
by: Abularrage, Nile S., et al.
Published: (2020)

Synthesis of pyridines and azaindoles via Diels-Alder reactions of tosyl cyanide with vinyl- and heteroarylallenes
by: Bartko, Samuel G.(Samuel Garrett)
Published: (2020)

Application of recyclable ionic liquid-supported imidazolidinone catalyst in enantioselective Diels–Alder reactions
by: Shen, Zhi-Liang, et al.
Published: (2013)

Enantioselective Diels–Alder reactions of enals and alkylidene diketones catalyzed by N-heterocyclic carbenes
by: Fang, Xinqiang, et al.
Published: (2014)

KINETICS OF THE LANGMUIRIAN ADSORPTION OF CUII IONS AT THE CALCITE WATER INTERFACE
by: Compton, R, et al.
Published: (1990)

Diastereo- and enantioselective synthesis of functionalized indolines via chiral counterion catalysis
by: Sharma, K, et al.
Published: (2013)

Theoretical insights into the enantioselectivity and mechanism of diels-alder reactions involving chiral cationic oxazaborolidinium catalyst
by: Omar, N.Y.M., et al.
Published: (2011)

The design and synthesis of polycyclic conjugated hydrocarbons via the incorporation of bifunctional Diels-Alder building blocks
by: Luppino, Sarah P. (Sarah Palmer)
Published: (2017)

Asymmetric synthesis of functionalized chiral diphosphines via organopalladium promoted hydrophosphination and diels-alder reactions
by: Yuan, Mingjun
Published: (2011)

Hyperconjugative Antiaromaticity Activates 4 H -Pyrazoles as Inverse-Electron-Demand Diels–Alder Dienes
by: Levandowski, Brian, et al.
Published: (2020)

Geminal repulsion disrupts Diels–Alder reactions of geminally substituted cyclopentadienes and 4H-pyrazoles
by: Levandowski, Brian J., et al.
Published: (2022)

A biocatalytic approach to enantioenriched hetero Diels-Alder adducts from beta-hydroxy ynones
by: Reiter, M, et al.
Published: (2005)

Bio‐inspired Domino oxa‐Michael/Diels–Alder/oxa‐Michael Dimerization of para‐Quinols
by: Green, N, et al.
Published: (2018)

A well-defined aluminum-based lewis acid as an effective catalyst for Diels-Alder transformations
by: Liu, Zhizhou, et al.
Published: (2015)

Diels-Alder exo selectivity in terminal-substituted dienes and dienophiles: experimental discoveries and computational explanations.
by: Lam, Y, et al.
Published: (2009)

Geminal Repulsion Disrupts Diels–Alder Reactions of Geminally Substituted Cyclopentadienes and 4H-Pyrazoles
by: Levandowski, Brian J, et al.
Published: (2022)

Reaction Pathway of the [4+ 2] Diels−Alder Adduct Formation on Si (100)−2 1
by: Minary, P, et al.
Published: (2004)