Acyloxylactonisations mediated by lead tetracarboxylates

The reaction of lead(IV) tetracarboxylates with carboxylic acids containing unsaturated side chains has been found to give acyloxy lactone products in a diastereoselective process; the reaction can be extended to lead(IV) tetrazolates to give the analogous outcome. Mechanistic implications of these...

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Main Authors: Cottrell, I, Cowley, A, Croft, L, Hymns, L, Moloney, M, Nettleton, E, Smithies, H, Thompson, A
Format: Journal article
Language:English
Published: 2009
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author Cottrell, I
Cowley, A
Croft, L
Hymns, L
Moloney, M
Nettleton, E
Smithies, H
Thompson, A
author_facet Cottrell, I
Cowley, A
Croft, L
Hymns, L
Moloney, M
Nettleton, E
Smithies, H
Thompson, A
author_sort Cottrell, I
collection OXFORD
description The reaction of lead(IV) tetracarboxylates with carboxylic acids containing unsaturated side chains has been found to give acyloxy lactone products in a diastereoselective process; the reaction can be extended to lead(IV) tetrazolates to give the analogous outcome. Mechanistic implications of these results are discussed. © 2009 Elsevier Ltd. All rights reserved.
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spelling oxford-uuid:ff44852f-2837-440d-af47-dd511ae6734c2022-03-27T13:43:32ZAcyloxylactonisations mediated by lead tetracarboxylatesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ff44852f-2837-440d-af47-dd511ae6734cEnglishSymplectic Elements at Oxford2009Cottrell, ICowley, ACroft, LHymns, LMoloney, MNettleton, ESmithies, HThompson, AThe reaction of lead(IV) tetracarboxylates with carboxylic acids containing unsaturated side chains has been found to give acyloxy lactone products in a diastereoselective process; the reaction can be extended to lead(IV) tetrazolates to give the analogous outcome. Mechanistic implications of these results are discussed. © 2009 Elsevier Ltd. All rights reserved.
spellingShingle Cottrell, I
Cowley, A
Croft, L
Hymns, L
Moloney, M
Nettleton, E
Smithies, H
Thompson, A
Acyloxylactonisations mediated by lead tetracarboxylates
title Acyloxylactonisations mediated by lead tetracarboxylates
title_full Acyloxylactonisations mediated by lead tetracarboxylates
title_fullStr Acyloxylactonisations mediated by lead tetracarboxylates
title_full_unstemmed Acyloxylactonisations mediated by lead tetracarboxylates
title_short Acyloxylactonisations mediated by lead tetracarboxylates
title_sort acyloxylactonisations mediated by lead tetracarboxylates
work_keys_str_mv AT cottrelli acyloxylactonisationsmediatedbyleadtetracarboxylates
AT cowleya acyloxylactonisationsmediatedbyleadtetracarboxylates
AT croftl acyloxylactonisationsmediatedbyleadtetracarboxylates
AT hymnsl acyloxylactonisationsmediatedbyleadtetracarboxylates
AT moloneym acyloxylactonisationsmediatedbyleadtetracarboxylates
AT nettletone acyloxylactonisationsmediatedbyleadtetracarboxylates
AT smithiesh acyloxylactonisationsmediatedbyleadtetracarboxylates
AT thompsona acyloxylactonisationsmediatedbyleadtetracarboxylates