Unravelling the key role of surface features behind facet-dependent photocatalysis of anatase TiO2

The high activity of nanocrystallites is commonly attributed to the terminal high-energy facets. However, we demonstrate that the high activity of the anatase TiO2(001) facet in photocatalytic H2 evolution is not due to its high intrinsic surface energy, but local electronic effects created by surfa...

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מידע ביבליוגרפי
Main Authors: Peng, Y-K, Keeling, B, Li, Y, Zheng, J, Chen, T, Chou, H-L, Puchtler, TJ, Taylor, RA, Tsang, SCE
פורמט: Journal article
שפה:English
יצא לאור: Royal Society of Chemistry 2019
תיאור
סיכום:The high activity of nanocrystallites is commonly attributed to the terminal high-energy facets. However, we demonstrate that the high activity of the anatase TiO2(001) facet in photocatalytic H2 evolution is not due to its high intrinsic surface energy, but local electronic effects created by surface features on the facet.