New chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile.
Pairing effect: Varying the concentration of support electrolyte in the electrochemical EC(2) reduction of 2,6-diphenylpyrylium reveals the presence of ion pairing between the electroactive species and BF(4)(-). Experiment and theory are shown to be in good agreement only if ion pairing is included...
| Váldodahkkit: | , , , |
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| Materiálatiipa: | Journal article |
| Giella: | English |
| Almmustuhtton: |
2012
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| _version_ | 1826307260330016768 |
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| author | Barnes, E Wang, Y Belding, SR Compton, R |
| author_facet | Barnes, E Wang, Y Belding, SR Compton, R |
| author_sort | Barnes, E |
| collection | OXFORD |
| description | Pairing effect: Varying the concentration of support electrolyte in the electrochemical EC(2) reduction of 2,6-diphenylpyrylium reveals the presence of ion pairing between the electroactive species and BF(4)(-). Experiment and theory are shown to be in good agreement only if ion pairing is included in the simulations. This previously unanticipated effect is only observable if voltammetry is performed under conditions of weak support. |
| first_indexed | 2024-03-07T07:00:14Z |
| format | Journal article |
| id | oxford-uuid:ff7da092-0990-4906-8f33-aaf298952dbd |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T07:00:14Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | oxford-uuid:ff7da092-0990-4906-8f33-aaf298952dbd2022-03-27T13:45:20ZNew chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ff7da092-0990-4906-8f33-aaf298952dbdEnglishSymplectic Elements at Oxford2012Barnes, EWang, YBelding, SRCompton, RPairing effect: Varying the concentration of support electrolyte in the electrochemical EC(2) reduction of 2,6-diphenylpyrylium reveals the presence of ion pairing between the electroactive species and BF(4)(-). Experiment and theory are shown to be in good agreement only if ion pairing is included in the simulations. This previously unanticipated effect is only observable if voltammetry is performed under conditions of weak support. |
| spellingShingle | Barnes, E Wang, Y Belding, SR Compton, R New chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile. |
| title | New chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile. |
| title_full | New chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile. |
| title_fullStr | New chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile. |
| title_full_unstemmed | New chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile. |
| title_short | New chemical insights using weakly supported voltammetry: ion pairing in the EC2 reduction of 2,6-diphenylpyrylium in acetonitrile. |
| title_sort | new chemical insights using weakly supported voltammetry ion pairing in the ec2 reduction of 2 6 diphenylpyrylium in acetonitrile |
| work_keys_str_mv | AT barnese newchemicalinsightsusingweaklysupportedvoltammetryionpairingintheec2reductionof26diphenylpyryliuminacetonitrile AT wangy newchemicalinsightsusingweaklysupportedvoltammetryionpairingintheec2reductionof26diphenylpyryliuminacetonitrile AT beldingsr newchemicalinsightsusingweaklysupportedvoltammetryionpairingintheec2reductionof26diphenylpyryliuminacetonitrile AT comptonr newchemicalinsightsusingweaklysupportedvoltammetryionpairingintheec2reductionof26diphenylpyryliuminacetonitrile |