Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din

Plant waste from coconut process output was investigated and develop into a new adsorbent. The raw spent grated coconut was modified to form xanthate-thiourea (XTSGC), and evaluated for treating Pb (II) and Ni (II) from binary metal ion system. Characteristic of XTSGC were investigated in the ana...

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Main Author: Mohd Din, Mohamad Nur Khairul Anwar
Format: Student Project
Language:English
Published: Faculty Of Applied Sciences 2017
Subjects:
Online Access:https://ir.uitm.edu.my/id/eprint/25551/1/PPb_MOHAMAD%20NUR%20KHAIRUL%20ANWAR%20MOHD%20DIN%20AS%20C%2017_5.PDF
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author Mohd Din, Mohamad Nur Khairul Anwar
author_facet Mohd Din, Mohamad Nur Khairul Anwar
author_sort Mohd Din, Mohamad Nur Khairul Anwar
collection UITM
description Plant waste from coconut process output was investigated and develop into a new adsorbent. The raw spent grated coconut was modified to form xanthate-thiourea (XTSGC), and evaluated for treating Pb (II) and Ni (II) from binary metal ion system. Characteristic of XTSGC were investigated in the analysis of FTIR, pH aqueous slurry and pH of zero point charge (pHzpc). The optimum pH for this biosorption process was found at pH 4. Equilibrium time for both metals was achieved after 90 minutes. For Pb (II), the pseudosecond order was agreed to kinetic data. The Freundlich isotherm model was fitted for Pb(II) isothenn adsorption equilibrium. Based on Freundlich model, the maximum adsorption capacity of Pb(II) was 0.59 mmol/g. The kinetic data from Ni (II) was also fitted to pseudo-second-order. The isothenn data for Ni (II) was well describe by Langmuir isotherm model. The monolayer adsorption capacity of Ni(II) was 0.24 mmol/L. Simultaneous removal of Pb (II) and Ni (II) were related to chemisorption mechanism such as complexation and ion-exchange.
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spelling uitm.eprints-55512019-09-19T08:29:58Z https://ir.uitm.edu.my/id/eprint/25551/ Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din Mohd Din, Mohamad Nur Khairul Anwar Extraction (Chemistry) Biotechnology Plant waste from coconut process output was investigated and develop into a new adsorbent. The raw spent grated coconut was modified to form xanthate-thiourea (XTSGC), and evaluated for treating Pb (II) and Ni (II) from binary metal ion system. Characteristic of XTSGC were investigated in the analysis of FTIR, pH aqueous slurry and pH of zero point charge (pHzpc). The optimum pH for this biosorption process was found at pH 4. Equilibrium time for both metals was achieved after 90 minutes. For Pb (II), the pseudosecond order was agreed to kinetic data. The Freundlich isotherm model was fitted for Pb(II) isothenn adsorption equilibrium. Based on Freundlich model, the maximum adsorption capacity of Pb(II) was 0.59 mmol/g. The kinetic data from Ni (II) was also fitted to pseudo-second-order. The isothenn data for Ni (II) was well describe by Langmuir isotherm model. The monolayer adsorption capacity of Ni(II) was 0.24 mmol/L. Simultaneous removal of Pb (II) and Ni (II) were related to chemisorption mechanism such as complexation and ion-exchange. Faculty Of Applied Sciences 2017 Student Project NonPeerReviewed text en https://ir.uitm.edu.my/id/eprint/25551/1/PPb_MOHAMAD%20NUR%20KHAIRUL%20ANWAR%20MOHD%20DIN%20AS%20C%2017_5.PDF Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din. (2017) [Student Project] <http://terminalib.uitm.edu.my/25551.pdf> (Unpublished)
spellingShingle Extraction (Chemistry)
Biotechnology
Mohd Din, Mohamad Nur Khairul Anwar
Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din
title Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din
title_full Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din
title_fullStr Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din
title_full_unstemmed Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din
title_short Competitive biosorption of pb (ll) and ni (ll) onto newly synthesized spongy xanthate-thiourea modified spent grated coconut / Mohamad Nur Khairul Anwar Mohd Din
title_sort competitive biosorption of pb ll and ni ll onto newly synthesized spongy xanthate thiourea modified spent grated coconut mohamad nur khairul anwar mohd din
topic Extraction (Chemistry)
Biotechnology
url https://ir.uitm.edu.my/id/eprint/25551/1/PPb_MOHAMAD%20NUR%20KHAIRUL%20ANWAR%20MOHD%20DIN%20AS%20C%2017_5.PDF
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