Natural dye sensitizer in dye sensitized solar cell

Blue-pea flower, turmeric, mulberries, brown rice, purple cabbage and Indian mulberry leave were successfully form on TiO2 mesoporous film using immersion method to produce TiO2 mesoporous photoanode for natural dye sensitized solar cells (DSSCs) assembly. The TiO2 mesoporous films were formed after...

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Main Authors: Nurain Najihah Alias, Khatijah Aisha Yaacob
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2016
Online Access:http://journalarticle.ukm.my/10181/1/08%20%20Nurain.pdf
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author Nurain Najihah Alias,
Khatijah Aisha Yaacob,
author_facet Nurain Najihah Alias,
Khatijah Aisha Yaacob,
author_sort Nurain Najihah Alias,
collection UKM
description Blue-pea flower, turmeric, mulberries, brown rice, purple cabbage and Indian mulberry leave were successfully form on TiO2 mesoporous film using immersion method to produce TiO2 mesoporous photoanode for natural dye sensitized solar cells (DSSCs) assembly. The TiO2 mesoporous films were formed after calcinations at 450˚C for 30 min. The photoanodes were dipped in different types of natural dye for 24, 72 and 120 h. The properties of natural dye were investigated by ultraviolet-visible spectroscopy (UV-vis) and Fourier transform infrared spectroscopy (FTIR). From UV-Vis spectroscopy analysis, the wavelength range of the natural dye studied in this research lays between 350 and 800 nm. The FTIR result of the natural dye shows the present of intermolecular H-bond, C=O stretching vibration, C-O-C stretching vibration, C=C bending and C-H bending which was due to the component of anthocyanin, carotenoids and chlorophyll. The characterization including field emission scanning electron microscopy (FESEM), energy dispersive x-ray (EDX) and x-ray diffraction (XRD) were carried out on the TiO2 mesoporous film. On the other hand, the conductivity of electrolyte for liquid electrolyte, gel electrolyte and solid electrolyte were also investigated. Gel electrolyte has the highest conductivity, 26.1 mS/cm while liquid electrolyte and solid electrolyte obtained 17.34 and 0.45 mS/cm, respectively. Finally, solar cells were prepared by sandwiching the TiO2 mesoporous photoanode with Platinum (Pt) counter electrode. The results showed short circuit current, open circuit current voltage, fill factor and efficiency for all samples during the present of light. The highest efficiency was obtained from Blue-pea sample that immersed for 120 h with 0.123% efficiency.
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spelling ukm.eprints-101812017-03-03T08:29:19Z http://journalarticle.ukm.my/10181/ Natural dye sensitizer in dye sensitized solar cell Nurain Najihah Alias, Khatijah Aisha Yaacob, Blue-pea flower, turmeric, mulberries, brown rice, purple cabbage and Indian mulberry leave were successfully form on TiO2 mesoporous film using immersion method to produce TiO2 mesoporous photoanode for natural dye sensitized solar cells (DSSCs) assembly. The TiO2 mesoporous films were formed after calcinations at 450˚C for 30 min. The photoanodes were dipped in different types of natural dye for 24, 72 and 120 h. The properties of natural dye were investigated by ultraviolet-visible spectroscopy (UV-vis) and Fourier transform infrared spectroscopy (FTIR). From UV-Vis spectroscopy analysis, the wavelength range of the natural dye studied in this research lays between 350 and 800 nm. The FTIR result of the natural dye shows the present of intermolecular H-bond, C=O stretching vibration, C-O-C stretching vibration, C=C bending and C-H bending which was due to the component of anthocyanin, carotenoids and chlorophyll. The characterization including field emission scanning electron microscopy (FESEM), energy dispersive x-ray (EDX) and x-ray diffraction (XRD) were carried out on the TiO2 mesoporous film. On the other hand, the conductivity of electrolyte for liquid electrolyte, gel electrolyte and solid electrolyte were also investigated. Gel electrolyte has the highest conductivity, 26.1 mS/cm while liquid electrolyte and solid electrolyte obtained 17.34 and 0.45 mS/cm, respectively. Finally, solar cells were prepared by sandwiching the TiO2 mesoporous photoanode with Platinum (Pt) counter electrode. The results showed short circuit current, open circuit current voltage, fill factor and efficiency for all samples during the present of light. The highest efficiency was obtained from Blue-pea sample that immersed for 120 h with 0.123% efficiency. Penerbit Universiti Kebangsaan Malaysia 2016-08 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/10181/1/08%20%20Nurain.pdf Nurain Najihah Alias, and Khatijah Aisha Yaacob, (2016) Natural dye sensitizer in dye sensitized solar cell. Sains Malaysiana, 45 (8). pp. 1227-1234. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid45bil8_2016/KandunganJilid45Bil8_2016.html
spellingShingle Nurain Najihah Alias,
Khatijah Aisha Yaacob,
Natural dye sensitizer in dye sensitized solar cell
title Natural dye sensitizer in dye sensitized solar cell
title_full Natural dye sensitizer in dye sensitized solar cell
title_fullStr Natural dye sensitizer in dye sensitized solar cell
title_full_unstemmed Natural dye sensitizer in dye sensitized solar cell
title_short Natural dye sensitizer in dye sensitized solar cell
title_sort natural dye sensitizer in dye sensitized solar cell
url http://journalarticle.ukm.my/10181/1/08%20%20Nurain.pdf
work_keys_str_mv AT nurainnajihahalias naturaldyesensitizerindyesensitizedsolarcell
AT khatijahaishayaacob naturaldyesensitizerindyesensitizedsolarcell