Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale

Latest advances of ionic liquids (ILs) have allowed to a new application on the dissolution of calcium carbonate (CaCO3) scales where the CaCO3 scale deposition have seriously severe threat in the petroleum field. In this study, the molecular interaction between CaCO3 and ILs n-pyridinium chloride [...

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Main Authors: Muhammad Suhaimi Man, Teo, Alvin Hua Huang, Syamsul Abdullah, Hanida Abdul Aziz, Mohd Hasbi Ab Rahim, Saifful Kamaluddin Muzakir, Norwahyu Jusoh
Format: Article
Language:English
Published: Penerbit Universiti Kebangsaan Malaysia 2022
Online Access:http://journalarticle.ukm.my/19751/1/14.pdf
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author Muhammad Suhaimi Man,
Teo, Alvin Hua Huang
Syamsul Abdullah,
Hanida Abdul Aziz,
Mohd Hasbi Ab Rahim,
Saifful Kamaluddin Muzakir,
Norwahyu Jusoh,
author_facet Muhammad Suhaimi Man,
Teo, Alvin Hua Huang
Syamsul Abdullah,
Hanida Abdul Aziz,
Mohd Hasbi Ab Rahim,
Saifful Kamaluddin Muzakir,
Norwahyu Jusoh,
author_sort Muhammad Suhaimi Man,
collection UKM
description Latest advances of ionic liquids (ILs) have allowed to a new application on the dissolution of calcium carbonate (CaCO3) scales where the CaCO3 scale deposition have seriously severe threat in the petroleum field. In this study, the molecular interaction between CaCO3 and ILs n-pyridinium chloride [NPy][Cl] was studied experimentally in order to get a better understanding during the dissolution of scale. NMR and FTIR spectroscopy was used to study the molecular interaction between CaCO3 and [NPy][Cl] solution during the dissolution process. To further evaluate the result, the simulation study using Gaussian software was utilized to predict in detail the molecular interaction between [Npy][Cl] and CaCO3. The finding from this study showed that the metal complex was formed via ligand after dissolution scale process. Based on the findings, it can be clinched that [Npy][Cl] has potential to be used as a scale dissolver in the oilfield, especially in dissolving calcium carbonate scales.
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spelling ukm.eprints-197512022-09-19T06:56:00Z http://journalarticle.ukm.my/19751/ Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale Muhammad Suhaimi Man, Teo, Alvin Hua Huang Syamsul Abdullah, Hanida Abdul Aziz, Mohd Hasbi Ab Rahim, Saifful Kamaluddin Muzakir, Norwahyu Jusoh, Latest advances of ionic liquids (ILs) have allowed to a new application on the dissolution of calcium carbonate (CaCO3) scales where the CaCO3 scale deposition have seriously severe threat in the petroleum field. In this study, the molecular interaction between CaCO3 and ILs n-pyridinium chloride [NPy][Cl] was studied experimentally in order to get a better understanding during the dissolution of scale. NMR and FTIR spectroscopy was used to study the molecular interaction between CaCO3 and [NPy][Cl] solution during the dissolution process. To further evaluate the result, the simulation study using Gaussian software was utilized to predict in detail the molecular interaction between [Npy][Cl] and CaCO3. The finding from this study showed that the metal complex was formed via ligand after dissolution scale process. Based on the findings, it can be clinched that [Npy][Cl] has potential to be used as a scale dissolver in the oilfield, especially in dissolving calcium carbonate scales. Penerbit Universiti Kebangsaan Malaysia 2022-06 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/19751/1/14.pdf Muhammad Suhaimi Man, and Teo, Alvin Hua Huang and Syamsul Abdullah, and Hanida Abdul Aziz, and Mohd Hasbi Ab Rahim, and Saifful Kamaluddin Muzakir, and Norwahyu Jusoh, (2022) Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale. Sains Malaysiana, 51 (6). pp. 1775-1787. ISSN 0126-6039 https://www.ukm.my/jsm/malay_journals/jilid51bil6_2022/KandunganJilid51Bil6_2022.html
spellingShingle Muhammad Suhaimi Man,
Teo, Alvin Hua Huang
Syamsul Abdullah,
Hanida Abdul Aziz,
Mohd Hasbi Ab Rahim,
Saifful Kamaluddin Muzakir,
Norwahyu Jusoh,
Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale
title Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale
title_full Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale
title_fullStr Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale
title_full_unstemmed Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale
title_short Molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale
title_sort molecular interaction study on a new application of ionic liquids as dissolver toward carbonate scale
url http://journalarticle.ukm.my/19751/1/14.pdf
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