Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid

ZnO/γ-Fe2O3 catalysts were fabricated via a simple precipitation route using zinc acetate and iron acetate as the precursors and ammonia as the precipitant. The resulted nanocatalysts were subjected to heat treatment at 450°C for 2 h. The characteristics of the nanocomposite were investigated by var...

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Main Authors: Lee, Kian Mun, Abdul Halim Abdullah, Mohd Zobir Hussein, Zulkarnain Zainal
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2014
Online Access:http://journalarticle.ukm.my/6930/1/14_Lee_Kian_Mun.pdf
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author Lee, Kian Mun
Abdul Halim Abdullah,
Mohd Zobir Hussein,
Zulkarnain Zainal,
author_facet Lee, Kian Mun
Abdul Halim Abdullah,
Mohd Zobir Hussein,
Zulkarnain Zainal,
author_sort Lee, Kian Mun
collection UKM
description ZnO/γ-Fe2O3 catalysts were fabricated via a simple precipitation route using zinc acetate and iron acetate as the precursors and ammonia as the precipitant. The resulted nanocatalysts were subjected to heat treatment at 450°C for 2 h. The characteristics of the nanocomposite were investigated by various characterization techniques. The synthesized nanocomposite has an average particle size of 13 nm and a surface area of 17 m2/g. The photocatalytic activity of ZnO/γ-Fe2O3 nanocomposite was evaluated by photodegrading 2,4-dichlorophenoxyacetic acid (2,4-D) under UV irradiation. The results showed that ZnO/γ-Fe2O3 nanocomposite exhibited enhanced photoactivity compared to pure ZnO with almost 20% increment within 4 h of reaction time. The result indicated the applicability of ZnO/γ-Fe2O3 nanocomposite to be used as photocatalyst in removing organic pollutants in wastewater.
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spelling ukm.eprints-69302016-12-14T06:42:37Z http://journalarticle.ukm.my/6930/ Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid Lee, Kian Mun Abdul Halim Abdullah, Mohd Zobir Hussein, Zulkarnain Zainal, ZnO/γ-Fe2O3 catalysts were fabricated via a simple precipitation route using zinc acetate and iron acetate as the precursors and ammonia as the precipitant. The resulted nanocatalysts were subjected to heat treatment at 450°C for 2 h. The characteristics of the nanocomposite were investigated by various characterization techniques. The synthesized nanocomposite has an average particle size of 13 nm and a surface area of 17 m2/g. The photocatalytic activity of ZnO/γ-Fe2O3 nanocomposite was evaluated by photodegrading 2,4-dichlorophenoxyacetic acid (2,4-D) under UV irradiation. The results showed that ZnO/γ-Fe2O3 nanocomposite exhibited enhanced photoactivity compared to pure ZnO with almost 20% increment within 4 h of reaction time. The result indicated the applicability of ZnO/γ-Fe2O3 nanocomposite to be used as photocatalyst in removing organic pollutants in wastewater. Universiti Kebangsaan Malaysia 2014-03 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/6930/1/14_Lee_Kian_Mun.pdf Lee, Kian Mun and Abdul Halim Abdullah, and Mohd Zobir Hussein, and Zulkarnain Zainal, (2014) Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid. Sains Malaysiana, 43 (3). pp. 437-441. ISSN 0126-6039 http://www.ukm.my/jsm/
spellingShingle Lee, Kian Mun
Abdul Halim Abdullah,
Mohd Zobir Hussein,
Zulkarnain Zainal,
Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid
title Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid
title_full Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid
title_fullStr Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid
title_full_unstemmed Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid
title_short Synthesis and photocatalysis of ZnO/γ-Fe2O3 nanocomposite in degrading herbicide 2,4-dichlorophenoxyacetic acid
title_sort synthesis and photocatalysis of zno γ fe2o3 nanocomposite in degrading herbicide 2 4 dichlorophenoxyacetic acid
url http://journalarticle.ukm.my/6930/1/14_Lee_Kian_Mun.pdf
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AT mohdzobirhussein synthesisandphotocatalysisofznogfe2o3nanocompositeindegradingherbicide24dichlorophenoxyaceticacid
AT zulkarnainzainal synthesisandphotocatalysisofznogfe2o3nanocompositeindegradingherbicide24dichlorophenoxyaceticacid