Determination of potential curves of Br2 in Franck-Condon’s region

The extinction of Br2 molecules in gas state is measured for different wavelengths of incident light in interval of 370 – 570 nm by method of gas spectroscopy. The measurement is made on the basis of Franck-Condon’s principle, under which a transition to a more excited state is done without changing...

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Main Authors: Janic, Edo S., Butigan, Vladimir, Novakovic, Jasmina Dj., Lekic, Milena
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2014
Online Access:http://journalarticle.ukm.my/7060/1/19_Edo_S._Janic.pdf
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author Janic, Edo S.
Butigan, Vladimir
Novakovic, Jasmina Dj.
Lekic, Milena
author_facet Janic, Edo S.
Butigan, Vladimir
Novakovic, Jasmina Dj.
Lekic, Milena
author_sort Janic, Edo S.
collection UKM
description The extinction of Br2 molecules in gas state is measured for different wavelengths of incident light in interval of 370 – 570 nm by method of gas spectroscopy. The measurement is made on the basis of Franck-Condon’s principle, under which a transition to a more excited state is done without changing the intercore distance (in further text, R). The graph of energy dependence on extinction is drawn. On the graph are recognized two Gausses slopes and their separation (deconvolution) is done. The complete Gausses functions are determined on graph. The method of mirror symmetry is applied on Gausses slopes of extinction and symmetrical extinction values (Es) are obtained. Borders of Franck-Condon’s area are determined from ground state of Linear Harmonic Oscillator (LHO). Tables of dependence on R and the excitation energy are given. On the basis of these tables are drawn potential curves of electron energy E(R) in excited electronic states of Br2 molecules as functions of R in Franck-Condon’s area.
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spelling ukm.eprints-70602016-12-14T06:42:59Z http://journalarticle.ukm.my/7060/ Determination of potential curves of Br2 in Franck-Condon’s region Janic, Edo S. Butigan, Vladimir Novakovic, Jasmina Dj. Lekic, Milena The extinction of Br2 molecules in gas state is measured for different wavelengths of incident light in interval of 370 – 570 nm by method of gas spectroscopy. The measurement is made on the basis of Franck-Condon’s principle, under which a transition to a more excited state is done without changing the intercore distance (in further text, R). The graph of energy dependence on extinction is drawn. On the graph are recognized two Gausses slopes and their separation (deconvolution) is done. The complete Gausses functions are determined on graph. The method of mirror symmetry is applied on Gausses slopes of extinction and symmetrical extinction values (Es) are obtained. Borders of Franck-Condon’s area are determined from ground state of Linear Harmonic Oscillator (LHO). Tables of dependence on R and the excitation energy are given. On the basis of these tables are drawn potential curves of electron energy E(R) in excited electronic states of Br2 molecules as functions of R in Franck-Condon’s area. Universiti Kebangsaan Malaysia 2014-04 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/7060/1/19_Edo_S._Janic.pdf Janic, Edo S. and Butigan, Vladimir and Novakovic, Jasmina Dj. and Lekic, Milena (2014) Determination of potential curves of Br2 in Franck-Condon’s region. Sains Malaysiana, 43 (4). pp. 637-642. ISSN 0126-6039 http://www.ukm.my/jsm/
spellingShingle Janic, Edo S.
Butigan, Vladimir
Novakovic, Jasmina Dj.
Lekic, Milena
Determination of potential curves of Br2 in Franck-Condon’s region
title Determination of potential curves of Br2 in Franck-Condon’s region
title_full Determination of potential curves of Br2 in Franck-Condon’s region
title_fullStr Determination of potential curves of Br2 in Franck-Condon’s region
title_full_unstemmed Determination of potential curves of Br2 in Franck-Condon’s region
title_short Determination of potential curves of Br2 in Franck-Condon’s region
title_sort determination of potential curves of br2 in franck condon s region
url http://journalarticle.ukm.my/7060/1/19_Edo_S._Janic.pdf
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