Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas

CaxZn(1-x)Al2O4 thin films (x = 0.00; 0.05; 0.10; 0.15 and 0.20) were prepared by sol-gel method with the substitution of Zn2+ by Ca2+ in the framework of ZnAl2O4. The effect of Ca addition on the structure and morphology of CaZnAl2O4 thin films was investigated by x-ray diffraction (XRD), field-emi...

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Main Authors: Wan Nasarudin Wan Jalal, Huda Abdullah, Mohd Syafiq Zulfakar, Sahbudin Shaari, Mohammad Thariqul Islam, Badariah Bais
Format: Article
Language:English
Published: Universiti Kebangsaan Malaysia 2014
Online Access:http://journalarticle.ukm.my/7171/1/04_Wan_Nasarudin.pdf
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author Wan Nasarudin Wan Jalal,
Huda Abdullah,
Mohd Syafiq Zulfakar,
Sahbudin Shaari,
Mohammad Thariqul Islam,
Badariah Bais,
author_facet Wan Nasarudin Wan Jalal,
Huda Abdullah,
Mohd Syafiq Zulfakar,
Sahbudin Shaari,
Mohammad Thariqul Islam,
Badariah Bais,
author_sort Wan Nasarudin Wan Jalal,
collection UKM
description CaxZn(1-x)Al2O4 thin films (x = 0.00; 0.05; 0.10; 0.15 and 0.20) were prepared by sol-gel method with the substitution of Zn2+ by Ca2+ in the framework of ZnAl2O4. The effect of Ca addition on the structure and morphology of CaZnAl2O4 thin films was investigated by x-ray diffraction (XRD), field-emission scanning electron microscope (FESEM), energy-dispersive x-ray spectroscopy (EDX), ultra-violet visible (UV-Vis) and atomic force microscope (AFM). The XRD patterns showed the characteristic peaks of face-centred cubic (fcc) ZnAl2O4 and CaZnAl2O4. The addition of Ca increased the crystallite size from 8.9 to 30.2 nm. The bandgap of CaxZn(1-x)Al2O4 thin film was found in the range of 3.40 to 3.84 eV. SEM micrograph shows the morphology of all thin films is sphere-like, with the grain size increased from 33 to 123 nm. The AFM images show the roughness of surface morphology increased. The substitution of Zn2+ by Ca2+ increased the crystallite size, grain size and surface roughness which evidently increased the density (4.59 to 4.64 g/cm3) and dielectric constant (8.48 to 9.54). The composition of CaxZn(1-x)Al2O4 is considered as suitable material for GPS patch antennas.
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spelling ukm.eprints-71712016-12-14T06:43:17Z http://journalarticle.ukm.my/7171/ Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas Wan Nasarudin Wan Jalal, Huda Abdullah, Mohd Syafiq Zulfakar, Sahbudin Shaari, Mohammad Thariqul Islam, Badariah Bais, CaxZn(1-x)Al2O4 thin films (x = 0.00; 0.05; 0.10; 0.15 and 0.20) were prepared by sol-gel method with the substitution of Zn2+ by Ca2+ in the framework of ZnAl2O4. The effect of Ca addition on the structure and morphology of CaZnAl2O4 thin films was investigated by x-ray diffraction (XRD), field-emission scanning electron microscope (FESEM), energy-dispersive x-ray spectroscopy (EDX), ultra-violet visible (UV-Vis) and atomic force microscope (AFM). The XRD patterns showed the characteristic peaks of face-centred cubic (fcc) ZnAl2O4 and CaZnAl2O4. The addition of Ca increased the crystallite size from 8.9 to 30.2 nm. The bandgap of CaxZn(1-x)Al2O4 thin film was found in the range of 3.40 to 3.84 eV. SEM micrograph shows the morphology of all thin films is sphere-like, with the grain size increased from 33 to 123 nm. The AFM images show the roughness of surface morphology increased. The substitution of Zn2+ by Ca2+ increased the crystallite size, grain size and surface roughness which evidently increased the density (4.59 to 4.64 g/cm3) and dielectric constant (8.48 to 9.54). The composition of CaxZn(1-x)Al2O4 is considered as suitable material for GPS patch antennas. Universiti Kebangsaan Malaysia 2014-06 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/7171/1/04_Wan_Nasarudin.pdf Wan Nasarudin Wan Jalal, and Huda Abdullah, and Mohd Syafiq Zulfakar, and Sahbudin Shaari, and Mohammad Thariqul Islam, and Badariah Bais, (2014) Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas. Sains Malaysiana, 43 (6). pp. 833-842. ISSN 0126-6039 http://www.ukm.my/jsm/
spellingShingle Wan Nasarudin Wan Jalal,
Huda Abdullah,
Mohd Syafiq Zulfakar,
Sahbudin Shaari,
Mohammad Thariqul Islam,
Badariah Bais,
Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas
title Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas
title_full Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas
title_fullStr Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas
title_full_unstemmed Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas
title_short Characteristics of nanostructured CaxZn(1-x)Al2O4 thin films prepared by Sol-Gel method for GPS patch antennas
title_sort characteristics of nanostructured caxzn 1 x al2o4 thin films prepared by sol gel method for gps patch antennas
url http://journalarticle.ukm.my/7171/1/04_Wan_Nasarudin.pdf
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