Graft copolymerization of acrylonitrile onto torch ginger cellulose
Graft copolymerization of acrylonitrile onto torch ginger cellulose was carried out in an aqueous medium with ceric ion redox initiator. The optimum grafting parameters such as temperature, reaction time, ratio of monomer to cellulose addition and ceric ammonium nitrate (CAN) concentration were dete...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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Universiti Kebangsaan Malaysia
2015
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| Online Access: | http://journalarticle.ukm.my/8965/1/11_Fazliyana.pdf |
| _version_ | 1796930881558937600 |
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| author | Fazliyana Ahmad Zaki, Ibrahim Abdullah, |
| author_facet | Fazliyana Ahmad Zaki, Ibrahim Abdullah, |
| author_sort | Fazliyana Ahmad Zaki, |
| collection | UKM |
| description | Graft copolymerization of acrylonitrile onto torch ginger cellulose was carried out in an aqueous medium with ceric ion redox initiator. The optimum grafting parameters such as temperature, reaction time, ratio of monomer to cellulose addition and ceric ammonium nitrate (CAN) concentration were determined and a maximum graft yield of 40% was recorded. The graft copolymer was characterized and compared with untreated cellulose. A new absorption peak corresponding to the nitrile group of acrylonitrile was recorded by FTIR at 2244 cm-1 on the grafted cellulose. The morphology studies showed that the diameter and the surface roughness of grafted cellulose had increased as compared with the untreated cellulose. On the contrary, the grafting had resulted in lowering the crystallinity of the cellulose from 63 to 53%. The grafted cellulose produced a new derivative TG peak at 420°C and higher residual percentage than the untreated cellulose. |
| first_indexed | 2024-03-06T04:09:45Z |
| format | Article |
| id | ukm.eprints-8965 |
| institution | Universiti Kebangsaan Malaysia |
| language | English |
| last_indexed | 2024-03-06T04:09:45Z |
| publishDate | 2015 |
| publisher | Universiti Kebangsaan Malaysia |
| record_format | dspace |
| spelling | ukm.eprints-89652016-12-14T06:48:34Z http://journalarticle.ukm.my/8965/ Graft copolymerization of acrylonitrile onto torch ginger cellulose Fazliyana Ahmad Zaki, Ibrahim Abdullah, Graft copolymerization of acrylonitrile onto torch ginger cellulose was carried out in an aqueous medium with ceric ion redox initiator. The optimum grafting parameters such as temperature, reaction time, ratio of monomer to cellulose addition and ceric ammonium nitrate (CAN) concentration were determined and a maximum graft yield of 40% was recorded. The graft copolymer was characterized and compared with untreated cellulose. A new absorption peak corresponding to the nitrile group of acrylonitrile was recorded by FTIR at 2244 cm-1 on the grafted cellulose. The morphology studies showed that the diameter and the surface roughness of grafted cellulose had increased as compared with the untreated cellulose. On the contrary, the grafting had resulted in lowering the crystallinity of the cellulose from 63 to 53%. The grafted cellulose produced a new derivative TG peak at 420°C and higher residual percentage than the untreated cellulose. Universiti Kebangsaan Malaysia 2015-06 Article PeerReviewed application/pdf en http://journalarticle.ukm.my/8965/1/11_Fazliyana.pdf Fazliyana Ahmad Zaki, and Ibrahim Abdullah, (2015) Graft copolymerization of acrylonitrile onto torch ginger cellulose. Sains Malaysiana, 44 (6). pp. 853-859. ISSN 0126-6039 http://www.ukm.my/jsm/malay_journals/jilid44bil6_2015/KandunganJilid44Bil6_2015.html |
| spellingShingle | Fazliyana Ahmad Zaki, Ibrahim Abdullah, Graft copolymerization of acrylonitrile onto torch ginger cellulose |
| title | Graft copolymerization of acrylonitrile onto torch ginger cellulose |
| title_full | Graft copolymerization of acrylonitrile onto torch ginger cellulose |
| title_fullStr | Graft copolymerization of acrylonitrile onto torch ginger cellulose |
| title_full_unstemmed | Graft copolymerization of acrylonitrile onto torch ginger cellulose |
| title_short | Graft copolymerization of acrylonitrile onto torch ginger cellulose |
| title_sort | graft copolymerization of acrylonitrile onto torch ginger cellulose |
| url | http://journalarticle.ukm.my/8965/1/11_Fazliyana.pdf |
| work_keys_str_mv | AT fazliyanaahmadzaki graftcopolymerizationofacrylonitrileontotorchgingercellulose AT ibrahimabdullah graftcopolymerizationofacrylonitrileontotorchgingercellulose |