Further studies on the chemistry of tetramethylthiourea-platinum complexes: Evolution of cis-[PtCl{S=C(NMe2)(2)}(PPh3)(2)](+) to the dinuclear monothiocarbamato-sulfido complex [Pt-2(mu-S){mu-SC(O)NMe2}(PPh3)(4)](+)

Further studies on the chemistry of tetramethylthiourea-platinum complexes: Evolution of cis-[PtCl{S=C(NMe2)(2)}(PPh3)(2)](+) to the dinuclear monothiocarbamato-sulfido complex [Pt-2(mu-S){mu-SC(O)NMe2}(PPh3)(4)](+)

Reaction of cis-[PtCl2(PPh3)(2)] with tetramethylthiourea (tmtu) in methanol under various conditions has been re-investigated. In the absence of base, the simple ligand substitution product [PtCl(tmtu)(PPh3)(2)]PF6 can be isolated by addition of excess NH4PF6. The complex was characterised by posit...

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Bibliographic Details
Main Authors:	Henderson, W., Nicholson, B.K., Fortney-Zirker, R.G., Patel, S., Lane, J.R., Wyllie, M.J., Tiekink, E.R.T.
Format:	Article
Published:	Elsevier 2015

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