Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction
Four metal complexes, namely [Cu(2)(ttzCOO)(2)(H(2)O)(4)]center dot 4H(2)O (1), [Zn(2)(ttzCOO)(2)(H(2)O)6]center dot 2H(2)O (2), [Pb(ttzCOO)(H(2)O)(2)](n) (3), and {[Cd(ttzCOO)(H(2)O)]center dot 1/2H(2)O}(n) (4), where ttzCOO(2-) = tetrazole-5-carboxylate dianion, have been prepared by the reaction...
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| פורמט: | Article |
| יצא לאור: |
Verlag Z Naturforsch
2010
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| נושאים: |
| _version_ | 1825720062933204992 |
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| author | Kou, Jun-Feng Su, M. Zhang, Yu-Hong Huang, Zhan-Dong Ng, S.W. Yang, G. |
| author_facet | Kou, Jun-Feng Su, M. Zhang, Yu-Hong Huang, Zhan-Dong Ng, S.W. Yang, G. |
| author_sort | Kou, Jun-Feng |
| collection | UM |
| description | Four metal complexes, namely [Cu(2)(ttzCOO)(2)(H(2)O)(4)]center dot 4H(2)O (1), [Zn(2)(ttzCOO)(2)(H(2)O)6]center dot 2H(2)O (2), [Pb(ttzCOO)(H(2)O)(2)](n) (3), and {[Cd(ttzCOO)(H(2)O)]center dot 1/2H(2)O}(n) (4), where ttzCOO(2-) = tetrazole-5-carboxylate dianion, have been prepared by the reaction of the sodium salt of 1H-tetrazole-5-carboxylic acid ethyl ester in aqueous methanolic solution at room temperature with CuCl(2), Znl(2), Pb(NO(3))(2), or Cd(NO(3))(2), respectively. The compounds were characterized by elemental analysis, IR spectroscopy, TG-DSC analysis and single-crystal X-ray diffraction. While 1 and 2 are structurally similar dinuclear complexes, 3 and 4 exhibit a ID chain structure and a 3D polymeric framework, respectively. |
| first_indexed | 2024-03-06T05:29:17Z |
| format | Article |
| id | um.eprints-11677 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:29:17Z |
| publishDate | 2010 |
| publisher | Verlag Z Naturforsch |
| record_format | dspace |
| spelling | um.eprints-116772017-05-22T06:40:59Z http://eprints.um.edu.my/11677/ Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction Kou, Jun-Feng Su, M. Zhang, Yu-Hong Huang, Zhan-Dong Ng, S.W. Yang, G. Q Science (General) Four metal complexes, namely [Cu(2)(ttzCOO)(2)(H(2)O)(4)]center dot 4H(2)O (1), [Zn(2)(ttzCOO)(2)(H(2)O)6]center dot 2H(2)O (2), [Pb(ttzCOO)(H(2)O)(2)](n) (3), and {[Cd(ttzCOO)(H(2)O)]center dot 1/2H(2)O}(n) (4), where ttzCOO(2-) = tetrazole-5-carboxylate dianion, have been prepared by the reaction of the sodium salt of 1H-tetrazole-5-carboxylic acid ethyl ester in aqueous methanolic solution at room temperature with CuCl(2), Znl(2), Pb(NO(3))(2), or Cd(NO(3))(2), respectively. The compounds were characterized by elemental analysis, IR spectroscopy, TG-DSC analysis and single-crystal X-ray diffraction. While 1 and 2 are structurally similar dinuclear complexes, 3 and 4 exhibit a ID chain structure and a 3D polymeric framework, respectively. Verlag Z Naturforsch 2010 Article PeerReviewed Kou, Jun-Feng and Su, M. and Zhang, Yu-Hong and Huang, Zhan-Dong and Ng, S.W. and Yang, G. (2010) Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction. Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences, 65 (12). pp. 1467-1471. |
| spellingShingle | Q Science (General) Kou, Jun-Feng Su, M. Zhang, Yu-Hong Huang, Zhan-Dong Ng, S.W. Yang, G. Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
| title | Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
| title_full | Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
| title_fullStr | Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
| title_full_unstemmed | Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
| title_short | Synthesis and crystal structures of Copper(II), Zinc(II), Lead(II) and Cadmium(II) Tetrazole-5-carboxylate complexes generated via in situ hydrolysis reaction |
| title_sort | synthesis and crystal structures of copper ii zinc ii lead ii and cadmium ii tetrazole 5 carboxylate complexes generated via in situ hydrolysis reaction |
| topic | Q Science (General) |
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