Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]]

In the coordination polymer, {(C2H8N)[Cd(CHO2)(3)]}(n), the Cd-II atom lies on a special position of (3) over bar site symmetry in an octahedron of O atoms. The formate unit bridges the metal atoms, generating a three-dimensional polyanionic framework. The disordered cations occupy the cavities with...

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Main Authors: Gao, S., Ng, S.W.
Format: Article
Published: International Union of Crystallography 2010
Subjects:
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author Gao, S.
Ng, S.W.
author_facet Gao, S.
Ng, S.W.
author_sort Gao, S.
collection UM
description In the coordination polymer, {(C2H8N)[Cd(CHO2)(3)]}(n), the Cd-II atom lies on a special position of (3) over bar site symmetry in an octahedron of O atoms. The formate unit bridges the metal atoms, generating a three-dimensional polyanionic framework. The disordered cations occupy the cavities within the framework, and are N-H center dot center dot center dot O hydrogen-bonded to the framework.
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spelling um.eprints-116882019-01-31T04:07:39Z http://eprints.um.edu.my/11688/ Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]] Gao, S. Ng, S.W. Q Science (General) In the coordination polymer, {(C2H8N)[Cd(CHO2)(3)]}(n), the Cd-II atom lies on a special position of (3) over bar site symmetry in an octahedron of O atoms. The formate unit bridges the metal atoms, generating a three-dimensional polyanionic framework. The disordered cations occupy the cavities within the framework, and are N-H center dot center dot center dot O hydrogen-bonded to the framework. International Union of Crystallography 2010 Article PeerReviewed Gao, S. and Ng, S.W. (2010) Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]]. Acta Crystallographica Section E: Structure Reports Online, 66 (12). M1599-U1082. ISSN 1600-5368,
spellingShingle Q Science (General)
Gao, S.
Ng, S.W.
Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]]
title Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]]
title_full Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]]
title_fullStr Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]]
title_full_unstemmed Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]]
title_short Poly[dimethylammonium [tris(mu(2)-formato-kappa O-2:O `)cadmate(II)]]
title_sort poly dimethylammonium tris mu 2 formato kappa o 2 o cadmate ii
topic Q Science (General)
work_keys_str_mv AT gaos polydimethylammoniumtrismu2formatokappao2ocadmateii
AT ngsw polydimethylammoniumtrismu2formatokappao2ocadmateii