Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II)
The Cu-II atom in the title compound, [Cu(C7H4IO2)(2)(C10H8N2)(H2O)], is N,N'-chelated by a 2,2'-bipyridine ligand and is coordinated by two monodentate carboxylate ions and a water molecule in a distorted square-pyramidal geometry. The apical site is occupied by one of the carboxylate O a...
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| Format: | Article |
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International Union of Crystallography
2010
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| author | Mohamadin, M.I. Abdullah, N. Lo, K.M. Ng, S.W. |
| author_facet | Mohamadin, M.I. Abdullah, N. Lo, K.M. Ng, S.W. |
| author_sort | Mohamadin, M.I. |
| collection | UM |
| description | The Cu-II atom in the title compound, [Cu(C7H4IO2)(2)(C10H8N2)(H2O)], is N,N'-chelated by a 2,2'-bipyridine ligand and is coordinated by two monodentate carboxylate ions and a water molecule in a distorted square-pyramidal geometry. The apical site is occupied by one of the carboxylate O atoms. The water molecule forms intramolecular hydrogen bonds to the uncoordinated carboxyl O atoms. The crystal studied was a nonmerohedral twin with minor components in 0.381 (3) and 0.108 (2) proportions. |
| first_indexed | 2024-03-06T05:29:19Z |
| format | Article |
| id | um.eprints-11689 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:29:19Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-116892019-01-31T04:44:54Z http://eprints.um.edu.my/11689/ Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II) Mohamadin, M.I. Abdullah, N. Lo, K.M. Ng, S.W. Q Science (General) The Cu-II atom in the title compound, [Cu(C7H4IO2)(2)(C10H8N2)(H2O)], is N,N'-chelated by a 2,2'-bipyridine ligand and is coordinated by two monodentate carboxylate ions and a water molecule in a distorted square-pyramidal geometry. The apical site is occupied by one of the carboxylate O atoms. The water molecule forms intramolecular hydrogen bonds to the uncoordinated carboxyl O atoms. The crystal studied was a nonmerohedral twin with minor components in 0.381 (3) and 0.108 (2) proportions. International Union of Crystallography 2010 Article PeerReviewed Mohamadin, M.I. and Abdullah, N. and Lo, K.M. and Ng, S.W. (2010) Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II). Acta Crystallographica Section E: Structure Reports Online, 66 (12). M1530-U495. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Mohamadin, M.I. Abdullah, N. Lo, K.M. Ng, S.W. Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II) |
| title | Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II) |
| title_full | Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II) |
| title_fullStr | Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II) |
| title_full_unstemmed | Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II) |
| title_short | Aqua(2,2 `-bipyridine-kappa N-2,N `)bis(4-iodobenzoato-kappa O)copper(II) |
| title_sort | aqua 2 2 bipyridine kappa n 2 n bis 4 iodobenzoato kappa o copper ii |
| topic | Q Science (General) |
| work_keys_str_mv | AT mohamadinmi aqua22bipyridinekappan2nbis4iodobenzoatokappaocopperii AT abdullahn aqua22bipyridinekappan2nbis4iodobenzoatokappaocopperii AT lokm aqua22bipyridinekappan2nbis4iodobenzoatokappaocopperii AT ngsw aqua22bipyridinekappan2nbis4iodobenzoatokappaocopperii |