(4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate
The V-V atom in the title compound, [V(C7H6ClN2O)(C16H11ClN2O3)O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazinylidene) propionate dianion. The distorted octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720065437204480 |
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| author | Wong, H.W. Lo, K.M. Ng, S.W. |
| author_facet | Wong, H.W. Lo, K.M. Ng, S.W. |
| author_sort | Wong, H.W. |
| collection | UM |
| description | The V-V atom in the title compound, [V(C7H6ClN2O)(C16H11ClN2O3)O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazinylidene) propionate dianion. The distorted octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds about a center of inversion, generating a dimer. |
| first_indexed | 2024-03-06T05:29:19Z |
| format | Article |
| id | um.eprints-11694 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:29:19Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-116942019-01-30T08:26:03Z http://eprints.um.edu.my/11694/ (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate Wong, H.W. Lo, K.M. Ng, S.W. Q Science (General) The V-V atom in the title compound, [V(C7H6ClN2O)(C16H11ClN2O3)O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazinylidene) propionate dianion. The distorted octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds about a center of inversion, generating a dimer. International Union of Crystallography 2010 Article PeerReviewed Wong, H.W. and Lo, K.M. and Ng, S.W. (2010) (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate. Acta Crystallographica Section E: Structure Reports Online, 66 (12). M1558-U726. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Wong, H.W. Lo, K.M. Ng, S.W. (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate |
| title | (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate |
| title_full | (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate |
| title_fullStr | (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate |
| title_full_unstemmed | (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate |
| title_short | (4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate |
| title_sort | 4 chlorobenzohydrazidato kappa n 2 o 2 4 chlorobenzoylhydrazinylidene kappa n 2 1 o 3 phenylpropionato 2 kappa o 1 oxidovanadium v methanol monosolvate |
| topic | Q Science (General) |
| work_keys_str_mv | AT wonghw 4chlorobenzohydrazidatokappan2o24chlorobenzoylhydrazinylidenekappan21o3phenylpropionato2kappao1oxidovanadiumvmethanolmonosolvate AT lokm 4chlorobenzohydrazidatokappan2o24chlorobenzoylhydrazinylidenekappan21o3phenylpropionato2kappao1oxidovanadiumvmethanolmonosolvate AT ngsw 4chlorobenzohydrazidatokappan2o24chlorobenzoylhydrazinylidenekappan21o3phenylpropionato2kappao1oxidovanadiumvmethanolmonosolvate |