2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate
The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796946282703486976 |
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| author | Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. |
| author_facet | Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. |
| author_sort | Gao, S. |
| collection | UM |
| description | The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)degrees. In the crystal, the cation, anion and water molecule interact by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network. |
| first_indexed | 2024-03-06T05:29:21Z |
| format | Article |
| id | um.eprints-11703 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:29:21Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-117032019-01-31T04:08:53Z http://eprints.um.edu.my/11703/ 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. Q Science (General) The cation of the title salt, C18H20N42+center dot 2HSO(4)(-)center dot 2H(2)O, lies on a center of inversion with the mid-point directly in the middle of the p-phenylene ring. Within the hydrogensulfate ion, the S-O(H) bond is the longest of the S-O bonds. The dihedral angle between the central and terminal ring of the cation is 78.6 (2)degrees. In the crystal, the cation, anion and water molecule interact by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Gao, S. and Qi, Xiao-Juan and Kong, Li-Li and Ng, S.W. (2010) 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate. Acta Crystallographica Section E: Structure Reports Online, 66 (12). O3300-U1823. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Gao, S. Qi, Xiao-Juan Kong, Li-Li Ng, S.W. 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
| title | 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
| title_full | 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
| title_fullStr | 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
| title_full_unstemmed | 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
| title_short | 2,2 `-[p-Phenylenebis(methylideneazanediyl)]dipyridinium bis(hydrogensulfate) dihydrate |
| title_sort | 2 2 p phenylenebis methylideneazanediyl dipyridinium bis hydrogensulfate dihydrate |
| topic | Q Science (General) |
| work_keys_str_mv | AT gaos 22pphenylenebismethylideneazanediyldipyridiniumbishydrogensulfatedihydrate AT qixiaojuan 22pphenylenebismethylideneazanediyldipyridiniumbishydrogensulfatedihydrate AT konglili 22pphenylenebismethylideneazanediyldipyridiniumbishydrogensulfatedihydrate AT ngsw 22pphenylenebismethylideneazanediyldipyridiniumbishydrogensulfatedihydrate |