N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne
The complete molecule of the title compound, C24H20Cl2N4, is generated by a crystallographic inversion centre. A kink in the molecule is evident [C-N-C-C torsion angle = -147.0 (3)degrees] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C = 1.2...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1825720067714711552 |
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| author | Prasath, R. Bhavana, P. Ng, S.W. Tiekink, E.R.T. |
| author_facet | Prasath, R. Bhavana, P. Ng, S.W. Tiekink, E.R.T. |
| author_sort | Prasath, R. |
| collection | UM |
| description | The complete molecule of the title compound, C24H20Cl2N4, is generated by a crystallographic inversion centre. A kink in the molecule is evident [C-N-C-C torsion angle = -147.0 (3)degrees] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) angstrom] and quinoline residues [N-C-C-C = -12.4 (4)degrees]. In the crystal, a combination of pi-pi [pyridine-benzene centroid-centroid distance = 3.5670 (14) angstrom] and C-H center dot center dot center dot N contacts leads to supramolecular chains propagating in [010]. |
| first_indexed | 2024-03-06T05:29:22Z |
| format | Article |
| id | um.eprints-11707 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:29:22Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-117072019-01-31T05:14:23Z http://eprints.um.edu.my/11707/ N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne Prasath, R. Bhavana, P. Ng, S.W. Tiekink, E.R.T. Q Science (General) The complete molecule of the title compound, C24H20Cl2N4, is generated by a crystallographic inversion centre. A kink in the molecule is evident [C-N-C-C torsion angle = -147.0 (3)degrees] owing to the twist in the central ethylene bridge. Further, there is a small twist between the imine [N=C = 1.267 (3) angstrom] and quinoline residues [N-C-C-C = -12.4 (4)degrees]. In the crystal, a combination of pi-pi [pyridine-benzene centroid-centroid distance = 3.5670 (14) angstrom] and C-H center dot center dot center dot N contacts leads to supramolecular chains propagating in [010]. International Union of Crystallography 2010 Article PeerReviewed Prasath, R. and Bhavana, P. and Ng, S.W. and Tiekink, E.R.T. (2010) N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne. Acta Crystallographica Section E: Structure Reports Online, 66 (12). O3123-U201. ISSN 1600-5368, |
| spellingShingle | Q Science (General) Prasath, R. Bhavana, P. Ng, S.W. Tiekink, E.R.T. N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne |
| title | N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne |
| title_full | N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne |
| title_fullStr | N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne |
| title_full_unstemmed | N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne |
| title_short | N,N `-Bis[(E)-(2-chloro-8-methylquinolin-3-yl)methylidene]ethane-1,2-diami ne |
| title_sort | n n bis e 2 chloro 8 methylquinolin 3 yl methylidene ethane 1 2 diami ne |
| topic | Q Science (General) |
| work_keys_str_mv | AT prasathr nnbise2chloro8methylquinolin3ylmethylideneethane12diamine AT bhavanap nnbise2chloro8methylquinolin3ylmethylideneethane12diamine AT ngsw nnbise2chloro8methylquinolin3ylmethylideneethane12diamine AT tiekinkert nnbise2chloro8methylquinolin3ylmethylideneethane12diamine |