Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).
In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal g...
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| Format: | Article |
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International Union of Crystallography
2010
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| _version_ | 1796944707836706816 |
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| author | Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Ali, Hapipah Mohd |
| author_facet | Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Ali, Hapipah Mohd |
| author_sort | Ikmal Hisham, Nurul Azimah |
| collection | UM |
| description | In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network. |
| first_indexed | 2024-03-06T05:05:43Z |
| format | Article |
| id | um.eprints-1190 |
| institution | Universiti Malaya |
| last_indexed | 2024-03-06T05:05:43Z |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | dspace |
| spelling | um.eprints-11902019-01-31T02:29:25Z http://eprints.um.edu.my/1190/ Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Ali, Hapipah Mohd QD Chemistry R Medicine In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network. International Union of Crystallography 2010 Article PeerReviewed Ikmal Hisham, Nurul Azimah and Suleiman Gwaram, Nura and Khaledi, Hamid and Ali, Hapipah Mohd (2010) Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). Acta Crystallographica Section E: Structure Reports Online, 67 (Pt 1). m55. ISSN 1600-5368, DOI 21522573. http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3050202/ 21522573 |
| spellingShingle | QD Chemistry R Medicine Ikmal Hisham, Nurul Azimah Suleiman Gwaram, Nura Khaledi, Hamid Ali, Hapipah Mohd Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). |
| title | Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). |
| title_full | Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). |
| title_fullStr | Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). |
| title_full_unstemmed | Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). |
| title_short | Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II). |
| title_sort | dichlorido 2 morpholino n 1 2 pyrid yl ethyl idene ethanamine κn n n zinc ii |
| topic | QD Chemistry R Medicine |
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